Education:
1983-1987, B.S., Department of Chemistry, Lanzhou University
1987-1990, M.S., Department of Chemistry, Lanzhou University
(Advisor: Prof. You-Cheng Liu)
1990-1993, Ph.D., Department of Chemistry, Lanzhou University
(Advisor: Prof. You-Cheng Liu)
Postdoctoral and Working
Experience:
1993-1995, Department of Chemistry, Fudan University
(Advisor: Prof. Shi-Hui Wu)
1995-1996, Institute for Chemical Research, Kyoto University (Advisor: Prof. Koichi
Komatsu)
1996-1997, Department of Chemistry, University of Kentucky
(Advisor: Prof. Mark S. Meier)
1997-1998, Department of Chemistry, University of Chicago
(Advisor: Prof. Philip E. Eaton)
1999-2000, Department of Chemistry, Yale University
(Advisor: Prof. Martin Saunders)
2000-
Department of Chemistry, University
of Science and Technology of China
2001.7-8,Visiting Professor, Institute for Chemical
Research, Kyoto
University
Research Interest:
Fullerene Chemistry, Green Organic Synthesis
Honors and Awards:
2005年获国务院特殊津贴
2005年获第七届安徽省青年科技奖
2007年获“药明康德生命化学研究奖”
科研项目:
1. 中国科学院“引进海外杰出人才”项目,200万元,2000-2003;
2. 国家杰出青年科学基金项目,80万元,2002-2005;
3.
国家自然科学基金重点项目“富勒烯骨架修饰及其应用研究”,300万,2012-2016
学术兼职:
《科学通报》编委(2002-)、《有机化学》编委(2007-)、《The Open Catalysis Journal》编委(2008-)、《影像科学与光化学》编委(2011-)
Professional Services:
Associate Editor, Chinese Science Bulletin (2002-)
Member of Editorial Board, Chinese Journal of Organic
Chemistry (2007-)
Member of Editorial Board, The Open Catalysis Journal
(2008-)
Member of Editorial Board, Imaging Science and
Photochemistry (2011-)
Selected Publications:
Fullerene Chemistry
27. Yang Xiao, San-E Zhu, Ding-Jia Liu, Mitsuaki Suzuki, Xing
Lu,* and Guan-Wu Wang,*
“Regioselective
Electrosynthesis of Rare 1,2,3,16-Functionalized [60]Fullerene
Derivatives”, Angew.
Chem. Int. Ed. 2014, 53,
4658-4662. Link to DOI:
10.1002/anie.201310565
26. Tong-Xin Liu, Tao Wei, San-E Zhu, Guan-Wu Wang,*
Mingzhi Jiao, Shangfeng Yang,* Faye L. Bowles, Marilyn M. Olmstead,* and
Alan L. Balch,* “Azide Addition to an Endohedral
Metallofullerene: Formation of Azafulleroids of Sc3N@Ih-C80”,
J. Am. Chem. Soc. 2012, 134, 11956-11959. Link to DOI:
10.1021/ja305446v
25. Guan-Wu Wang,* Tong-Xin Liu, Mingzhi Jiao, Nan Wang,
San-E Zhu, Chuanbao Chen, Shangfeng Yang,* Faye L. Bowles, Christine M.
Beavers, Marilyn M. Olmstead,* Brandon Q. Mercado, and Alan L. Balch,*
“The Cycloaddition Reaction of Ih-Sc3N@C80
with 2-Amino-4,5-diisopropoxybenzoic Acid and Isoamyl Nitrite in Air to
Produce an Open-Cage Metallofullerene”, Angew.
Chem. Int. Ed. 2011, 50,
4658-4662; Angew. Chem. 2011, 123, 4754-4758. Link to DOI:
10.1002/ange.201100510
24.Xun You and Guan-Wu Wang,* “Ferric
Chloride-Catalyzed Reaction of [60]Fullerene with tert-Butyl N-Substituted
Carbamates: Synthesis of Oxazolidino[4,5:1,2][60]fullerenes”, J. Org. Chem. 2014, 79, 117-121. Links
to DOI:
10.1021/jo402354w
23.Rui Liu, Fei Li, Yang Xiao, Dan-Dan Li, Cheng-Lin
He, Wei-Wei Yang, Xiang
Gao,* and Guan-Wu Wang,* “Electroreductive
Transformation of [60]Fullerosultones into Fullerosulfonic Acids”, J. Org. Chem. 2013, 78, 7093-7099. Links
to DOI:
10.1021/jo400920f
22. Cheng-Lin He, Rui Liu, Dan-Dan Li, San-E Zhu, and Guan-Wu Wang,* “Synthesis
and Functionalization of [60]Fullerene-Fused Imidazolines”, Org. Lett. 2013, 15, 1532-1535. Link to DOI:
10.1021/ol400319w
21.
Fa-Bao
Li, Xun You, and Guan-Wu Wang,* “Ferric Perchlorate-Mediated Synthesis of 1,2-Fullerenols
C60(OCOR)(OH)”, J. Org. Chem. 2012, 77, 6643-6647. Link to DOI: 10.1021/jo301202g
20. Fa-Bao
Li, Xun You, Tong-Xin Liu, and Guan-Wu Wang,* “Fullerenyl Boronic Esters: Ferric Perchlorate-Mediated
Synthesis and Functionalization”, Org. Lett. 2012, 14, 1800-1803. Link to DOI:
10.1021/ol300398n
19. Tong-Xin
Liu, Fa-Bao Li, and Guan-Wu Wang,* “Synthesis of [60]Fullerene-Fused
Tetrahydronaphthalene and Indane Derivatives via a Pathway Switched by
Aluminum Chloride”, Org. Lett. 2011, 13, 6130-6133. Link to DOI:
10.1021/ol202645z
18. Guan-Wu Wang,*
Cong-Zhou Wang, and Jian-Ping Zou, “Radical Reaction of
[60]Fullerene with Phosphorus Compounds Mediated by Manganese(III)
Acetate”, J. Org. Chem. 2011, 76, 6088-6094. Link to DOI: 10.1021/jo2007384
17. Guan-Wu Wang,*
Cong-Zhou Wang, San-E Zhu, and Yasujiro Murata,* “Manganese(III)
Acetate-Mediated Radical Reaction of [60]Fullerene with Phosphonate
Esters Affording Unprecedented Separable Singly-Bonded [60]Fullerene
Dimers”, Chem. Commun. 2011, 47, 6111-6113. Link to DOI:
10.1039/C1CC10820D
16. Fa-Bao
Li, Xun You, and Guan-Wu Wang,* “Synthesis of Disubstituted
[60]Fullerene-Fused Lactones: Ferric Perchlorate-Promoted Reaction of
[60]Fullerene with Malonate Esters”, Org.
Lett. 2010, 12, 4896-4899. Link to DOI:
10.1021/ol102056k. Highlighted by Synfacts 2011, 1, 0038.
15. Fa-Bao Li, Tong-Xin Liu, Xun You, and Guan-Wu Wang*,
“A Facile Access to [60]Fullerene-Fused 1,3-Dioxolanes: Reaction of
[60]Fullerene with Aldehydes/Ketones Promoted by Ferric Perchlorate”, Org. Lett. 2010, 12, 3258-3261. Link to DOI:
10.1021/ol101206u
14. Fa-Bao Li, Tong-Xin Liu, Yong-Shun Huang, Guan-Wu
Wang*, “Synthesis of Fullerene-Fused Lactones and Fullerenyl
Esters: Radical Reaction of [60]Fullerene with Carboxylic Acids Promoted
by Manganese(III) Acetate and Lead(IV) Acetate”, J. Org. Chem. 2009,
74, 7743-7749. Link
to DOI:
10.1021/jo901028x
13. Guan-Wu Wang,* Yong-Ming Lu, Zhong-Xiu Chen, Shi-Hui
Wu, “An Alternative Type of Fullerene Products from the Reaction
of [60]Fullerene with Alkoxides and Subsequent Derivatization”, J. Org. Chem. 2009,
74, 4841-4847. Link
to DOI:
10.1021/jo9005848
12. Bo Zhu, Guan-Wu Wang,* “Synthesis of
[60]Fulleroindolines: Palladium-Catalyzed Heteroannulations of
[60]Fullerene with o-Iodoanilines”, J. Org.
Chem. 2009, 74,
4426-4428. Link
to DOI:
10.1021/jo900585u
11. Guan-Wu Wang,* Yong-Ming Lu, Zhong-Xiu Chen, “1,4-Fullerenols
C60ArOH: Synthesis and Functionalization”, Org. Lett. 2009,
11, 1507-1510. Link
to DOI:
10.1021/ol900110g
10.
Guan-Wu Wang,* Bo Zhu, “A Facile Access
to [60]Fullerene-Fused δ-Lactones: Unexpected Reaction Pathway of
Benzenediazonium-2-carboxylates Controlled by Organic Bases”, Chem. Commun. 2009,
1769-1771. Link
to DOI:
10.1039/B820395D
9. Fa-Bao Li, Tong-Xin Liu, Guan-Wu Wang*, “Synthesis of Fullerooxazoles: Novel Reactions of
[60]Fullerene with Nitriles Promoted by Ferric Perchlorate ”, J. Org. Chem. 2008,
73, 6417-6420. Link
to DOI:
10.1021/jo8007868
8. Guan-Wu Wang*, Fa-Bao Li, Zhong-Xiu Chen, Ping Wu, Bin
Cheng, Yu Xu, “Synthesis
of [60]Fullerene Acetals and Ketals: Reaction of [60]Fullerene with
Aldehydes/Ketones and Alkoxides”, J. Org. Chem. 2007,
72, 4779-4783. Link
to DOI:
10.1021/jo070387p
7. Guan-Wu Wang*, Fa-Bao Li, Yu Xu, “Novel Functionalizations of
[60]Fullerene-Fused Lactones”, J. Org. Chem. 2007, 72, 4774-4778. Link to DOI:
10.1021/jo070386x
6. Guan-Wu Wang*, Xiao-Ping Chen, Xin Cheng, “Unexpected Reactions
of [60]Fullerene Involving Tertiary Amines and Insight into the Reaction
Mechanisms”, Chem. Eur. J. 2006, 12, 7246-7253. Link to DOI:
10.1002/chem.200600575
5.
Guan-Wu Wang*, Hai-Tao Yang, Ping Wu, Chun-Bao
Miao, Yu Xu, “Novel Cycloaddition
Reaction of [60]Fullerene with Carbonyl Ylides Generated from Epoxides”, J. Org. Chem. 2006,
71, 4346-4348. Link
to DOI:
10.1021/jo060427+
4.
Guan-Wu Wang*, Fa-Bao Li, Ting-Hu Zhang,
“[60]Fullerene-Fused Lactones: Manganese(III) Acetate-Mediated Synthesis
and Novel Reductive Ring Opening”, Org. Lett. 2006, 8, 1355-1358. Link to DOI:
10.1021/ol060090y
3.
Guan-Wu Wang*, Jia-Xing, Li, Yu-Jin Li,
You-Cheng Liu, “Novel Reactions
of [60]Fullerene with Amino Acid Esters and Carbon Disulfide”, J. Org. Chem. 2006, 71, 680-684. Link to DOI:
10.1021/jo052116p
2.
Zhong-Xiu Chen, Guan-Wu Wang*, “One-Pot Sequential Synthesis of Acetoxylated [60]Fullerene Derivatives”, J. Org. Chem. 2005,
70, 2380-2383. Link
to DOI:
10.1021/jo047894g
1. Guan-Wu Wang*, Xin-Hao Zhang, Huan Zhan, Qing-Xiang Guo,
Yun-Dong Wu, “Accurate Calculation, Prediction, and
Assignment of 3He NMR Chemical Shifts of Helium-3-Encapsulated
Fullerenes and Fullerene Derivatives”, J.
Org. Chem. 2003, 68,
6732-6738. Link
to DOI:
10.1021/jo0341259
Green Organic Synthesis
Ø
C–H
Bond Activation
13. Guan-Wu Wang,*
Ting-Ting Yuan, Dan-Dan Li, “One-Pot Cascade C–C and C–N Bond Formation via
Palladium-Catalyzed Dual C–H Activations: Synthesis of
Phenanthridinones”, Angew. Chem. Int. Ed. 2011,
50, 1380-1383; Angew. Chem. 2011, 123,
1416-1419. Link
to DOI:
10.1002/ange.201005874. Highly cited paper by ISI; Most accessed
articles in Jan 2011; Highlighted by Synfacts 2011, 4, 0429 and
Chin. J. Org. Chem. 2011, 31, 592.
12. Wen-Qiang Zhai, Ru-Fang Peng, Bo Jin, and Guan-Wu Wang,* “Synthesis
of [60]Fullerene-Fused Tetrahydrobenzooxepine and Isochroman Derivatives
via Hydroxyl-Directed C–H Activation/C–O Cyclization”, Org. Lett. 2014, 15, Articles ASAP. Link to DOI:
10.1021/ol5002818
11. Tao-Shan Jiang and Guan-Wu Wang,* “Synthesis of
2-Acylthiophenes by Palladium-Catalyzed Addition of Thiophenes to
Nitriles”, Adv.
Synth. Catal. 2014, 356,
369-373.
Link to DOI:
10.1002/adsc.201300843
10.
Zhong-Yuan Li, Dan-Dan Li, and Guan-Wu Wang,* “Palladium-Catalyzed
Decarboxylative Ortho Acylation of Azobenzenes with α-Oxocarboxylic
Acids”, J.
Org. Chem. 2013, 78,
10414-10420 Link to DOI:
10.1021/jo401794a
9. Tao-Shan Jiang and Guan-Wu Wang,* “Synthesis of
3-Acylindoles by Palladium-Catalyzed Acylation of Free (N–H) Indoles with
Nitriles”, Org.
Lett. 2013, 15, 788-791. Link to DOI:
10.1021/ol303440y The
most read articles from Organic Letters between January and March 2013
8. Tao-Shan Jiang and Guan-Wu Wang,* “Palladium-Catalyzed
Ortho-Alkoxylation of Anilides via C-H Activation”, J. Org. Chem. 2012, 77, 9504-9509
Link
to DOI: 10.1021/jo301964m. (Feature Article)
7. Yi-Tan
Su, You-Liang Wang, and Guan-Wu Wang,* “Palladium-Catalysed
Heteroannulation of [60]Fullerene with N-Benzyl Sulfonamides and
Subsequent Functionalisation”, Chem. Commun.
2012, 48, 8132-8134. Link to DOI:
10.1039/C2CC33923D. (Invited article for the
themed issue: Aromaticity)
6. Fei Li,
Xun You, Tong-Xin Liu, and Guan-Wu Wang,* “Synthesis of [60]Fullerene-Fused
Sultones via Sulfonic Acid Group-Directed C–H Bond Activation”, Org. Lett. 2012, 14, 2176-2179. Link to DOI:
10.1021/ol3007452
5. Dan-Dan
Li, Ting-Ting Yuan, and Guan-Wu Wang,* “Palladium-Catalyzed
Ortho-Arylation of Benzamides via Direct sp2 C–H Bond Activation”, J. Org. Chem. 2012,
77, 3341-3347. Link
to DOI:
10.1021/jo300126n
4. Dan-Dan
Li, Ting-Ting Yuan, and Guan-Wu Wang,* “Synthesis of Isoindolinones via
Palladium-Catalyzed C–H Activation of N-Methoxybenzamides”, Chem. Commun. 2011, 47, 12789-12791. Link to DOI:
10.1039/C1CC15897J (Top
ten most accessed articles in November, 2011)
3. Guan-Wu
Wang,* Ting-Ting Yuan,
“Palladium-Catalyzed Alkoxylation of N-Methoxybenzamides via Direct
sp2 C–H Bond Activation”, J. Org.
Chem. 2010, 75,
476-479. Link
to DOI:
10.1021/jo902139b
2. Bo Zhu,
Guan-Wu Wang,*
“Palladium-Catalyzed Heteroannulation of [60]Fullerene with Anilides via
C−H Bond Activation”, Org. Lett. 2009, 11, 4334-4337. Link to DOI:
10.1021/ol901675t
1. Guan-Wu Wang,*
Ting-Ting Yuan, Xue-Liang Wu, “Direct Ortho-Acetoxylation of Alinides via
Palladium-Catalyzed sp2 C-H Bond Oxidative Activation”, J. Org. Chem. 2008,
73, 4717-4720. Link
to DOI:
10.1021/jo8003088 (Highlighted
by Organic Chemistry Portal:
http://www.organic-chemistry.org/abstracts/lit2/150.shtm)
Ø
Mechanochemistry--Solvent-Free Organic Reactions
13. Guan-Wu
Wang*, “Mechanochemical
Organic Synthesis”, Chem. Soc. Rev., 2013, 42, 7668-7700. Link to DOI:
10.1039/C3CS35526H (Invited review
article for the themed collection: Mechanochemistry).
12. San-E Zhu, Fei Li and Guan-Wu Wang*, “Mechanochemistry of
Fullerenes and Related Materials”, Chem. Soc.
Rev., 2013, 42, 7535-7570. Link to DOI:
10.1039/C3CS35494F (Front Cover & Invited review article
for the themed collection: Mechanochemistry).
11. Yi-Tan
Su and Guan-Wu Wang, “FeCl3-Mediated
Cyclization of [60]Fullerene with N-Benzhydryl
Sulfonamides under High-Speed Vibration Milling Conditions”, Org. Lett. 2013, 15, 3408-3411. Link to DOI:
10.1021/ol4014602
10. Guang-Peng Fan, Zi Liu, and Guan-Wu Wang,* “An efficient
ZnBr2-catalyzed reactions of allylic alcohols with indoles,
sulfamides and anilines under high-speed vibration
milling conditions”, Green Chem. 2013, 15, 1659-1664. Link to DOI:
10.1039/c3gc40262b
9. Zi Liu, Guang-Peng Fan and Guan-Wu Wang,* “Unexpected
manganese(III) acetate-mediated reactions of β-enamino carbonyl compounds
with 1-(pyridin-2-yl)-enones under mechanical milling conditions”, Chem. Commun. 2012, 48, 11665-11667. Link to DOI:
10.1039/C2CC36360G. (Invited
article the ChemComm ‘Mechanochemistry’ web themed issue)
8. Guan-Wu
Wang* and Jie Gao, “Solvent-Free
Bromination Reactions with Sodium Bromide and Oxone Promoted by
Mechanical Milling”, Green Chem. 2012,
14, 1125-1131. Link
to DOI:
10.1039/C2GC16606B
7. Guan-Wu
Wang,* Jie Gao, “Selective
Formation of Spiro Dihydrofurans and Cyclopropanes Through Unexpected
Reaction of Aldehydes with 1,3-Dicarbonyl Compounds”, Org. Lett. 2009,
11, 2385-2388. Link
to DOI:
10.1021/ol900451d
6. Guan-Wu Wang,* Ya-Wei Dong, Ping Wu, Ting-Ting Yuan,
Ye-Bing Shen, “Unexpected Solvent-Free Cycloadditions of
1,3-Cyclohexanediones to 1-(Pyridin-2-yl)-enones Mediated by Manganese
(III) Acetate in a Ball Mill”, J. Org. Chem. 2008, 73, 7088-7095. Link to DOI: 10.1021/jo800870z
5. Guan-Wu Wang,* Jie Gao, “Direct Oxidative
Amidation of Aldehydes with Anilines Under Mechanical Milling
Conditions”, J. Org. Chem. 2008, 73, 2955-2958. Link to DOI:
10.1021/jo800075t
4. Xue-Liang Wu, Guan-Wu Wang,* “Mechanochemical
Aminochlorination of Electron-Deficient Olefins with Chloramine-T
Promoted by PhI(OAc)2”, Adv.
Synth. Catal. 2007, 349,
1977-1982. Link
to DOI:
10.1002/adsc.200700020
3. Guan-Wu Wang,* Chun-Bao Miao, “Environmentally
Benign One-Pot Multi-Component Approaches to the Synthesis of Novel
Unsymmetrical 4-Arylacridinediones”, Green
Chem. 2006, 8,
1080-1085. Link
to DOI:
10.1039/B604064K
2.
Ze Zhang, Chun-Bao Miao, Ya-Wei Dong, Ye-Bing
Shen, Guan-Wu Wang,* “Solid-state Radical Reactions of 1,3-Cyclohexanediones
with in situ Generated Imines Mediated by Manganese(III) Acetate
under Mechanical Milling Conditions”, Chem.
Commun. 2004,
1832-1833. Link to DOI:
10.1039/B406402J
1. Guan-Wu Wang, “Fullerene Mechanochemistry”,
in Encyclopedia of Nanoscience and
Nanotechnology, H. S. Nalwa, Ed., American Scientific Publishers: Stevenson Ranch, Vol. 3, p.
557-565, 2004. (invited book chapter).
Ø
Others
3. San-E Zhu, Yan-Min Kuang, Feng Geng, Jia-Zhe Zhu,
Cong-Zhou Wang, Yun-Jie Yu, Yang Luo, Yang Xiao, Kai-Qing Liu, Qiu-Shi
Meng, Li Zhang, Song Jiang, Yang Zhang, Guan-Wu Wang,* Zhen-Chao Dong,*
J. G. Hou “Self-Decoupled Porphyrin with a Tripodal
Anchor for Molecular Scale Electroluminescence”, J. Am. Chem. Soc. 2013,
135, 15794-15780. Link
to DOI:
10.1021/ja4048569
2. Tao Miao and Guan-Wu
Wang,* “Synthesis of Ketones by Palladium-Catalysed
Desulfitative Reaction of Arylsulfinic Acids with Nitriles”, Chem. Commun. 2011,
47, 9501-9503. Link
to DOI:
10.1039/C1CC13352G
1. Guan-Wu Wang* and Tao Miao, “Palladium-Catalyzed
Desulfitative Heck-Type Reaction of Arylsulfinic Acids with Alkenes”, Chem. Eur. J. 2011, 17,
5787-5790. Link
to DOI:
10.1002/chem.201100539
Ø
Representative Publications prior to USTC
7.
Koichi Fujiwara, Koichi Komatsu*, Guan-Wu Wang,
Kazunori Yamamoto, and Martin Saunders, "Derivatzation of Fullerene
Dimer C120 by the Bingle Reaction and a 3He NMR
study of 3He@C120 Monoadduct", J. Am. Chem.
Soc. 2001, 123, 10715-10720.
6. Yves
Rubin,* Thibaut Jarrosson, Guan-Wu
Wang, Michael D. Bartberger, Kendall N. Houk,* Georg Schick,
Martin Saunders,* and R. James Cross,* “Insertion of Helium and Molecular
Hydrogen Inside an Open Fullerene”, Angew.
Chem. Int. Ed. 2001, 40, 1543-1546.
5.
Guan-Wu Wang, Martin Saunders,* and R. James Cross,*
“Reversible Diels-Alder Addition to Fullerenes. A Study of Equilibrium
using 3He NMR”, J. Am. Chem. Soc. 2001, 123,
256-259.
4.
Guan-Wu Wang, Martin Saunders,* Anthony
Khong, and R. James Cross, “A New Method for
Separating the Isomeric C84 Fullerenes”, J. Am. Chem. Soc. 2000,
122, 3216-3217.
3. Andrew
F. Kiely, Robert C. Haddon,* Mark S. Meier,* John P. Selegue; Carolyn
Pratt Brock,* Brian O. Patrick, Guan-Wu
Wang, and Yongsheng Chen, “The First Structurally Characterized
Homofullerene (Fulleroid): 7,8-Dichloromethanohomo[70]fullerene”, J. Am. Chem. Soc. 1999, 121, 7971-7972.
2.
Mark S. Meier,* Guan-Wu Wang, Robert C. Haddon, Carolyn Pratt Brock, Michael
A. Lloyd, and John P. Selegue, “Benzyne Adds Across a Closed 5-6 Ring
Fusion in C70: Evidence for Bond Delocalization in
Fullerenes”, J. Am. Chem. Soc. 1998, 120, 2337-2342.
1.
Guan-Wu Wang,
Koichi Komatsu,* Yasujiro Murata, and Motoo Shiro, “Synthesis and X-Ray Structure
of Dumb-Bell-Shaped C120”, Nature
1997, 387, 583-586.
Click
here to see a full list of
publications.
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中国科学技术大学 刘有成 院士
中国科学技术大学 郭庆祥 教授
中国科学技术大学 汪志勇 教授
京都大学 小松纮一(Koichi
Komatsu) 教授
肯塔基大学
Mark S. Meier
教授
芝加哥大学
Philip E. Eaton 教授
耶鲁大学
Martin Saunders
院士
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