112.Visible-Light-Induced Synthesis of Azlactone Monomers and Dimers utilizing SF6 as both Condensation Agent and Oxidant
Zhi-Yuan Liu, Yan He, Yi-Gang Yang, Ruo-Xing Jin*, Shan Zhu*, Xi-Sheng Wang*
Org. Lett. 2025, 27, 1, 41–45
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111.CF2H-synthon enables asymmetric radical difluoroalkylation for synthesis of chiral difluoromethylated amines
Peng Liu, Yan He, Chen-Hui Jiang, Wei-Ran Ren, Ruo-Xing Jin, Ting Zhang, Wang-Xuan Chen, Xuan Nie*, Xi-Sheng Wang*
Nat Commun 16, 599 (2025)
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109.Remote Functionalization of Inert C(sp3)–H Bonds via Dual Catalysis Driven by Alkene Hydrofluoroalkylation Using Industrial Feedstocks
Yan He, Kang-Jie Bian, Peng Liu, Chen-Hui Jiang, Ruo-Xing Jin, Julian G. West* and Xi-Sheng Wang*
Org. Lett. 2024, 26, 39, 8278–8283
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108.Visible light-induced photocatalytic deoxyfluorination of benzyl alcohol using SF6 as a fluorinating reagent
Yi-Fan Zhang, Shan Zhu, Ya-Wen Zuo, Hang Liu, Ruo-Xing Jin*, and Xi-Sheng Wang*
Green Chem., 2024,26, 10324-10329
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107.Regio- and enantioselective hydroalkylation of alkynes via nickel-alkyl insertion for modular synthesis of chiral allylic amines
Qian Gao, Wei-Cheng Xu, Xuan Nie, Kang-Jie Bian, Hong-Rui Yuan, Wen Zhang, Bing-Bing Wu*, and Xi-Sheng Wang*
Nat Commun 15, 6556 (2024)
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106.Visible-Light-Induced Oxidative Decarboxylative Coupling of Phenylacetic Acid Derivatives Using SF6 as an Oxidant
Ya-Wen Zuo, Yue Zhao, Yi-Fan Zhang, Xiao-Yu Guo, Tian-Rui Wu, Ruo-Xing Jin*, and Xi-Sheng Wang*
Org. Lett. 2024, 26, 27, 5652–5656
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105.Development of SF6 as a Formal Electrophilic Fluorinating Reagent for Photocatalyzed Oxidative Fluorination of Phosphine Oxides
Yu-Ling Huang, Qing-Qing Zhang, Cheng-Yu Wang*, Yue Zhao*, and Xi-Sheng Wang*
Org. Lett. 2024, 26, 27, 5776–5781
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104.Photoredox Catalyzed Synthesis of gem-Difluoroalkenes and Monofluorinated Cyclooctenes via 1,5-HAT Process
Yuan-Bo Li, Yu-Lin Wang, Qian Gao, Jing-Cheng Dai, Ruo-Xing Jin*, and Xi-Sheng Wang*
Org. Lett. 2024, 26, 21, 4548–4553
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103.Visible-Light-Induced Oxidation of Silanes with SF6 for Efficient Synthesis of Siloxanes
Yu-Xiang Bi, Yue Zhao, Qing-Qing Zhang, Xiao-Yu Guo, Jing-Cheng Dai, Ruo-Xing Jin*, Xi-Sheng Wang*
Eur. J. Org. Chem. 2024, e202400451
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102.Tailoring d-band center of high-valent metal-oxo species for pollutant removal via complete polymerization
Hong-Zhi Liu, Xiao-Xuan Shu, Mingjie Huang*, Bing-Bing Wu, Jie-Jie Chen*, Xi-Sheng Wang, Hui-Lin Li & Han-Qing Yu*
Nat Commun 15, 2327 (2024)
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101.Enantioselective Construction of C-SCF3 Stereocenters via Nickel Catalyzed Asymmetric Negishi Coupling Reaction
Duo-Duo Hu, Tian-Mei Nie, Xi Xiao, Kuiliang Li, Yuan-Bo Li, Qian Gao, Yu-Xiang Bi, Xi-Sheng Wang*
Angew. Chem. Int. Ed. 2024, e202400308
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2023
100.A bivalent inhibitor against TDRD3 to suppress phase separation of methylated G3BP1
Wei-Wei Fan, Tian Xu, Jia Gao, Han-Yu Zhang, Yan Li, Duo-Duo Hu, Shuaixin Gao, Jia-Hai Zhang, Xing Liu, Dan Liu, Pi-Long Li, Catherine C. L. Wong, Xue-Biao Yao, Yun-Yu Shi, Zhen-Ye Yang, Xi-Sheng Wang* and Ke Ruan*
Chem. Commun., 2024, Advance Article
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99.Nickel-catalyzed reductive coupling reaction of monofluoroalkyl triflates with alkyl carboxylic acids toward the synthesis of α-alkyl-α-fluoro-alkylketones
Rui Wang, Jie Xu, Jin-Xiao Li, Bing-Bing Wu, Ruo-Xing Jin, Yu-Xiang Bi, Xi-Sheng Wang*
Chin. Chem. Lett. 2023, 34, 10, 108490
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98.Nickel-Catalyzed Asymmetric Decarboxyarylation with NHP Esters of α-Amino Acid to Chiral Benzylamines
Cheng-Yu Wang, Yu-Ling Huang, Wei-Cheng Xu, Qian Gao, Peng Liu, Yu-Xiang Bi, Guo-Kai Liu*, and Xi-Sheng Wang*
Org. Lett. 2023, 25, 38, 6964–6968
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97.Enantioselective catalytic radical decarbonylative azidation and cyanation of aldehydes
Rui Wang, Cheng-Yu Wang, Peng Liu, Kang-Jie Bian, Chi Yang, Bing-Bing Wu, and Xi-Sheng Wang*
Sci. Adv. 2023, 9, 35, eadh5195
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96.Photoinduced Copper-Catalyzed Monofluoroalkylation of Terminal Alkynes to Propargylic Fluorides
Duo-Duo Hu, Chao Li, Qian Gao, Tian-Mei Nie, Kai-Fan Zhang, Bing-Bing Wu, Yan Li*, and Xi-Sheng Wang*
Org. Lett. 2023, 25, 24, 4514-4519
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95.Copper/ Photoredox dual Catalyzed Syntheses of Allenenitrilesvia 1,5-HAT
Yuan-Bo Li, Yu-Xiang Bi, Wen-Chang Ke, Cheng-Yu Wang,Duo-Duo Hu, Yan Li, and Xi-Sheng Wang
Asian J. Org. Chem2023, e202300234.
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94.Synthesis of trifluoromethylated thioethers via Ni-catalyzed reductive C-S coupling
Wei Liu, Yan He, Zhi-Yuan Liu, Yanlin Li, Yan Li, Bing-Bing Wu, Ruo-Xin Jin and Xi-Sheng Wang*
Org. Chem. Front., 2023, ASAP.
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93.Nickel-Catalyzed Hydrotrifluoroalkylation of Alkynes to Construct Allylic Trifluoromethyl Terminal Alkenes
Ting Zhang, Ya-Wen Zuo, Ruo-Xing Jin, Yi-Fan Zhang, Bing-Bing Wu,* and Xi-Sheng Wang*
Org. Lett. 2023, 25, 3578-3584.
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2022
92.Asymmetric construction of allylicstereogenic carbon center featuring atrifluoromethyl group via enantioselective reductive fluoroalkylation
Ruo-Xing Jin#, Bing-Bing Wu#, Kang-Jie Bian, Jian-Liang Yu, Jing-Cheng Dai, Ya-Wen Zuo, Yi-Fan Zhang, Xi-Sheng Wang*
Nat. Commun., 2022, 13, 7035.
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91.A General and Efficient Solution to Monofluoroalkylation: Divergent Synthesis of Aliphatic Monofluorides with Modular Synthetic Scaffolds
Bing-Bing Wu, Jie Xu, Qian Gao, Kang-Jie Bian, Guo-Kai Liu*, Xi-Sheng Wang*
Angew. Chem. Int. Ed. 2022, e202208938.
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90.Nickel-catalyzed hydromonofluoromethylation of unactivated alkenes for expedient construction of primary alkyl fluorides
Shan-Xiu Ni, Yan-LinLi, Hui-Qi Ni, Yu-Xiang Bi, Jie Sheng, Xi-Sheng Wang*
Chin. Chem. Lett. 2022, 10.1016/j.cclet.2022.06.037.
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89.Modular Difunctionalization of Unactivated Alkenes through Bio-Inspired Radical Ligand Transfer Catalysis
Kang-Jie Bian, David Nemoto Jr., Shih-Chieh Kao, Yan He, Yan Li, Xi-Sheng Wang*, and Julian G. West*
J. Am. Chem. Soc. 2022, 144, 11810-11821.
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88.Enantioselective Synthesis of Secondary β-Trifluoromethyl Alcohols via Catalytic Asymmetric Reductive Trifluoroalkylation and Diastereoselective Reduction
Bing-Bing Wu#, Jie Xu#, Kang-Jie Bian, Qian Gao, and Xi-Sheng Wang*
J. Am. Chem. Soc. 2022, 144, 14, 6543-6550.
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87.Ligand-Promoted, Enantioconvergent Synthesis of Aliphatic Alkanes Bearing Trifluoromethylated Stereocenters via Hydrotrifluoroalkylation of Unactivated Alkenes
Yan He, Kang-Jie Bian, Bing-Bing Wu, Peng Liu, Shan-Xiu Ni, and Xi-Sheng Wang*
Chin. J. Chem. 2022, 40, 1531-1536.
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85.Selective 1,4-arylsulfonation of 1,3-enynes via photoredox/nickel dual catalysis.
Chao Li, Duo-Duo Hu, Ruo-Xing Jin, Bing-Bing Wu, Cheng-Yu Wang,
Zhuofeng Ke* and Xi-Sheng Wang* Org. Chem. Front., 2022,9, 788-794. DOI: 10.1039/d1qo01653a
84.Development of Monofluoroalkenes as Molecular Platform for DiversityOriented Syntheses of Tertiary Aliphatic Fluorides via Nickel/Manganese-Dual Catalysis.
Yanlin Li, Wei Liu, Zhi-Yuan Liu, Cheng-Yu Wang, Kang-Jie Bian, Jie Sheng, and Xi-Sheng Wang* CCS Chem. 2021, 3, 3320–3328. DOI：10.31635/ccschem.021.202101395
83.Facile Synthesis of Quaternary alfa-Fluoronitriles by Cobalt-Catalyzed Hydrocyanation of Monofluoroalkenes Yanlin Li, Ru Cui, Tian-Rui Wu, and Xi-Sheng Wang* Synthesis 2021, 53, A–J. DOI：10.1055/s-0040-1719841
82.Development of Axially Chiral Styrene-Type Carboxylic Acid Ligands via Palladium-Catalyzed Asymmetric C–H Alkynylation Chi Yang#, Fei Li#, Tian-Rui Wu, Ru Cui, Bing-Bing Wu, Ruo-Xing Jin, Yan Li, and Xi-Sheng Wang* Org. Lett. 2021, 23, 21, 8132–8137 DOI：10.1021/acs.orglett.1c02692
81.Copper-Catalyzed Enantioselective Arylation via Radical-Mediated C–C Bond Cleavage: Synthesis of Chiral ω,ω-Diaryl Alkyl Nitriles Guo-Qing Cui, Jing-Cheng Dai, Yan Li, Yuan-Bo Li, Duo-Duo Hu, Kang-Jie Bian, Jie Sheng, and Xi-Sheng Wang* Org.Lett., 2021, 23, 7503-7507 DOI：10.1021/acs.orglett.1c02725
80.Nickel-catalyzed reductive monofluoroakylation of alkyl tosylate with bromofluoromethane to primary alkyl fluoride Ru Cui#,Jie Sheng#, Bing-Bing Wu, Duo-Duo Hu, Hong-Qian Zheng and Xi-Sheng Wang* Chem. Commun., 2021, 57, 9084 - 9087 DOI：10.1039/d1cc02837e
79.Nickel-Catalyzed Cross-Coupling of Ethyl Chlorofluoroacetate with Aryl Bromides Han Li#, Jie Sheng#, Bing-Bing Wu, Yan Li, and Xi-Sheng Wang* Chem Asian J. 2021, 16, 1741–1744 DOI：10.1002/asia.202100348
78.Copper-Catalyzed Mon-ochloromethyl-azidation to Ac-cess Transform-able Terminal Alkyl Chlorides Using Stoichio-metric BrCH2Cl Ya-Xuan Zhang, Kang-Jie Bian, Ruoxing Jin, Chi Yang and Xi-Sheng Wang* Chem. Commun., 2021，57, 5666-5669 DOI：10.1039/D1CC01751a
77.Improved enantioselectivity in thiol–ene photopolymerization of sulphur-containing polymers with circularly polarized luminescence Chen-Lu He#, Zeyu Feng#, Yan Li#, Manman Zhou, Liyang Zhao, Sizhen Shan, Mengqiao Wang, Xin Chen*, Xi-Sheng Wang* and Gang Zou* Polym. Chem., 2021, 12, 2433–2438 DOI: 10.1039/d1py00082a
76.Diversity‐Oriented Synthesis of Aliphatic Fluorides via Reductive C(sp3)–C(sp3) Cross‐Coupling Fluoroalkylation Jie Sheng#，Hui-Qi Ni#，Shan-Xiu Ni，Yan He，Ru Cui， Guang-Xu Liao，Kang-Jie Bian，Bing-Bing Wu，and Xi-Sheng Wang* Angew. Chem. Int. Ed. 2021, 60, 15020-15027 DOI:10.1002/anie.202102481
75.Diverse Synthesis of Chiral Trifluoromethylated Alkanes via NickelCatalyzed Asymmetric Reductive Cross-Coupling Fluoroalkylation Yue Min#, Jie Sheng#, Jian-Liang Yu, Shan-Xiu Ni, Guo-bin Ma, He-gui Gong, and Xi-Sheng Wang* Angew. Chem. Int. Ed. 2021, 60, 9947 –9952 DOI:10.1002/anie.202101076
74.Copper-Catalyzed Trifluoromethylation/Cyclization of Alkynes for Synthesis of Dioxodibenzothiazepines Zi-Qi Zhang, Yi-Hao Xu, Jing-Cheng Dai, Yan Li, Jie Sheng, and Xi-Sheng Wang* Org. Lett.,2021, 23, 2194–2198 DOI: 10.1021/acs.orglett.1c00344
73.Facile synthesis of axially chiral styrene-type carboxylic acids via palladium-catalyzed asymmetric C–H activation Chi Yang, Tian-Rui Wu, Yan Li, Bing-Bing Wu, Ruo-Xing Jin, Duo-Duo Hu, Yuan-Bo Li, Kang-Jie Bian and Xi-Sheng Wang* Chemical Science, 2021, 12, 3726–3732. DOI: 10.1039/d0sc06661c
2020
72.Copper-Catalyzed Intramolecular Amination of C(sp3)−H Bond of Secondary Amines to Access Azacycles Ruo-Xing Jin, Jing-Cheng Dai, Yan Li*, and Xi-Sheng Wang* Org. Lett. 2021, 23, 421−426 DOI: 10.1021/acs.orglett.0c03934
71.Rh(III)‐Catalyzed N‐Nitroso Directed C‐H Arylation for Facile Construction of Diverse N‐Hetero Biaryl Compounds. Pei-Long Wang#, Yan Wang#, Yan Li,* and Xi-Sheng Wang* Chem Asian J. 2020, 15, 3825 –3828 DOI: 10.1002/asia.202000949
70.Nickel-Catalyzed Direct Trifluoroethylation of Aryl Iodides with 1,1,1-Trifluoro-2-Iodoethane via Reductive Coupling Han Li, Jie Sheng, Guang-Xu Liao, Bing-Bing Wu, Hui-Qi Ni, Yan Li and Xi-Sheng Wang* Adv.Synth.Catal. 2020, 362, 5363-5367 DOI: 10.1002/adsc.202000985.
69.Iron-catalyzed remote functionalization of inert C(sp3)–H bonds of alkenes via 1,n-hydrogen-atomtransfer by C-centered radical relay Kang-Jie Bian#, Yan Li#, Kai-Fan Zhang, Yan He, Tian-Rui Wu, Cheng-Yu Wangand Xi-Sheng Wang* Chem. Sci., 2020, 11, 10437–10443 DOI: 10.1039/d0sc03987j.
68.Palladium(II)-catalyzed asymmetric C–H carbonylation to diverse isoquinoline derivativesbearing all-carbon quaternary stereocenters† Yan Li, Xiu-Fen Cheng, Fan Fei, Tian-Rui Wu, Kang-Jie Bian, Xin Zhou andXi-Sheng Wang * Chem. Commun., 2020, 56, 11605-11608 DOI: 10.1039/d0cc05219a.
67.Ligand-Accelerated Palladium(II)-Catalyzed Enantioselective Amination of C(sp2)−H Bonds Xiu-Fen Cheng#, Fan Fei#, Yan Li,* Yi-Ming Hou, Xin Zhou, and Xi-Sheng Wang* Org. Lett. 2020, 22, 16, 6394–6398 DOI: 10.1021/acs.orglett.0c02216.
65.Enantioselective Copper-Catalyzed Remote C(sp3)−H Alkynylation of Linear Primary Sulfonamides Cheng-Yu Wang#, Zi-Yang Qin#, Yu-Ling Huang, Yi-Ming Hou, Ruo-Xing Jin, Chao Li, and Xi-Sheng Wang* Org. Lett. 2020, 22, 10, 4006–4009 DOI: 10.1021/acs.orglett.0c01325.
2019
64.Visible light-mediated atom transfer radical addition to styrene: base controlled selective (phenylsulfonyl)difluoromethylation Jie Sheng#, Kang-Jie Bian#, Yi-Ming Su, Guang-Xu Liao,Ruomeng Duan, Chen Li,Zhihong Liu* and Xi-Sheng Wang* Org. Chem. Front., 2020, 7, 617 DOI: 10.1039/c9qo01433k
63.Enantioselective Copper-Catalyzed Cyanation of Remote C(sp3)-H Bonds Enabled by 1,5-Hydrogen Atom Transfer Cheng-Yu Wang#, Zi-Yang Qin#, Yu-Ling Huang, Ruo-Xing Jin, Quan Lan, and Xi-Sheng Wang* iScience 21, 490–498, November 22, 2019 DOI：10.1016/j.isci.2019.10.048
62.Enantioselective cyanation via radical-mediated C–C single bond cleavage for synthesis of chiral dinitriles Tao Wang, Yi-Ning Wang, Rui Wang, Bo-Chao Zhang, Chi Yang, Yan-Lin Li and Xi-Sheng Wang * Nat Commun 10, 5373 (2019) DOI:10.1038/s41467-019-13369-x
61.NHC Ligand-Enabled, Palladium-Catalyzed Non-Directed C(sp3)−H Carbonylation To Access Indanone Cores Shou-Le Cai, Yan Li, Chi Yang, Jie Sheng, and Xi-Sheng Wang* ACS Catal. 2019, 9, 10299−10304 DOI: 10.1021/acscatal.9b03426
60.Enantioselective Copper-Catalyzed 1,5-Cyanotrifluoromethylation of Vinylcyclopropanes Zi-Qi Zhang, Xiang-Yu Meng, Jie Sheng, Quan Lan and Xi-Sheng Wang* Org. Lett.2019, 21, 20, 8256-8260 DOI: 10.1021/acs.orglett.9b03012
59.Highly Stereoselective Nickel-Catalyzed Difluoroalkylation of Aryl Ketones to Tetrasubstituted Monofluoroalkenes and Quaternary Alkyl Difluorides Chao Li#, Yi-Xuan Cao#, Ruo-Xing Jin, Kang-Jie Bian, Zi-Yang Qin, Quan Lan and Xi-Sheng Wang * Chem. Sci., 2019, 10, 9285-9251 DOI: 10.1039/C9SC02806D
58.Nickel-catalyzed monofluoromethylation of (hetero)aryl bromides via reductive cross-coupling Han Yin#, Jie Sheng#, Kai-Fan Zhang, Zi-Qi Zhang, Kang-Jie Bian and Xi-Sheng Wang* Chem. Commun., 2019, 55, 7635 DOI: 10.1039/c9cc03737c
57.Nickel-Catalyzed Carbofluoroalkylation of 1,3-Enynes to Access Structurally Diverse Fluoroalkylated Allenes Kai-Fan Zhang, Kang-Jie Bian, Chao Li, Jie Sheng, Yan Li, and Xi-Sheng Wang* Angew Chem Int Ed. 2019, 58, 5069-5074 DOI:10.1002/anie.201813184
2018
56. Cobalt-catalyzed difluoroalkylation of tertiary aryl ketones for facile synthesis of quaternary alkyl difluorides Chao Li#, Yi-Xuan Cao#, Rui Wang, Yi-Ning Wang, Quan Lan and Xi-Sheng Wang* Nat. Commun. 2018, 9, 4951. DOI: 10.1038/s41467-018-07525-y.
55. Copper-Catalyzed Dichloromethylazidation of Alkenes Using BrCCl2H as a Stoichiometric Dichloromethylating Reagent Ya-Xuan Zhang, Ruo-Xing Jin, Han Yin, Yan Li, and Xi-Sheng Wang* Org. Lett. 2018, 20, 7283-7287. DOI: 10.1021/acs.orglett.8b03208.
54. Trifluoromethylthiolation/Oxidation of Styrenes for Facile Synthesis of α-Trifluoromethylthio Acetophenons Jian-Yong Wang#, Lan Ma#, Yan Li, Xi-Sheng Wang* Chinese Journal of Organic Chemistry 2019, 39. DOI: 10.6023/cjoc201807052.
53. Palladium(II)-Catalyzed C(sp2)−H Carbonylation of Sterically Hindered Amines with Carbon Monoxide Xiu-Fen Cheng#, Tao Wang#, Yan Li,* Yun Wu, Jie Sheng, Rui Wang, Chao Li, Kang-Jie Bian, and Xi-Sheng Wang* Org. Lett. 2018, 20, 6530−6533. DOI: 10.1021/acs.orglett.8b02856.
52. Rhodium(III)-Catalyzed C-H Alkynylation of N-Methylsulfoximines Tao Wang, Yi-Ning Wang, Rui Wang, and Xi-Sheng Wang* Chem Asian J 2018, 13, 2449-2452. DOI: 10.1002/asia.201800889.
50. Nickel-Catalyzed Reductive Cross-Coupling of Aryl Halides with Monofluoroalkyl Halides for Late-Stage Monofluoroalkylation Jie Sheng#, Hui-Qi Ni#, Hao-Ran Zhang, Kai-Fan Zhang, Yi-Ning Wang and Xi-Sheng Wang* Angew. Chem., Int. Ed. 2018, 57, 7634-7639. DOI: 10.1002/anie.201803228.
49. Terminal C(sp3)-H alkylation of internal alkenes via Ni/H-catalyzed isomerization Zhen-Yu Wang, Jia-Hao Wan, Gao-Yin Wang, Rui Wang, Ruo-Xing Jin, Quan Lan, Xi-Sheng Wang* Tetrahedron Lett. 2018, 59, 2302-2305. DOI: 10.1016/j.tetlet.2018.05.008.
48. Nickel-Catalyzed Heck-Type Monofluoroacetation of Styrenes for Facile Synthesis of Allylic Fluorides Zhen-Yu Wang, Jia-Hao Wan, Gao-Yin Wang, Ruo-Xing Jin, Quan Lan, and Xi-Sheng Wang* Chem. Asian J., 2018, 13, 261–265. DOI: 10.1002/asia.201701655.
47. Copper-catalyzed formylation of alkenyl C–H bonds using BrCHCl2 as a stoichiometric formylating reagent† Yan Bao, Gao-Yin Wang, Ya-Xuan Zhang, Kang-Jie Bian and Xi-Sheng Wang * Chem. Sci., 2018, 9, 2986–2990. DOI: 10.1039/c8sc00210j.
46.Palladium-Catalyzed Enantioselective C-H Olefination of Diaryl Sulfoxides through Parallel Kinetic Resolution and Desymmetrization Yu-Chao Zhu#, Yan Li#, Bo-Chao Zhang, Feng-Xu Zhang, Yi-Nuo Yang, and Xi-Sheng Wang* Angew. Chem. Int. Ed. 2018, 57, 5129 –5133. DOI: 10.1002/anie.201801146.
45. Nickel-catalyzed direct difluoromethylation of aryl boronic acids with BrCF2H Jie Sheng, Hui-Qi Ni, Kang-Jie Bian, Yan Li, Yi-Ning Wang, Xi-Sheng Wang* Org. Chem. Front. 2018,5, 606-610 . DOI: 10.1039/C7QO00934H.
2017
44. Copper-Catalyzed Aerobic [1,3]-Nitrogen Shift via Nitrogen Radical 4-Exo-Trig Cyclization Yan Li#, Rui Wang#, Xiu-Fen Cheng, Tao Wang, Xin Zhou, Fan Fei, Xi-Sheng Wang* Angew. Chem. Int. Ed. 2017, 56(48), 15436-15440.
43. Novel and facile synthesis of 1-benzazepines via copper-catalyzed oxidative C(sp3)–H/C(sp2)–H cross-coupling Rui Wang, Ruo-Xing Jin, Zi-Yang Qin, Kang-Jie Bian, Xi-Sheng Wang* Chem. Commun. 2017, 53(90), 12229-12232.
42. Combinatorial Nickel-Catalyzed Monofluoroalkylation of Aryl Boronic Acids with Unactivated Fluoroalkyl Iodide Jie Sheng, Hui-Qi Ni, Ge Liu, Yan Liu, Xi-Sheng Wang* Org. Lett. 2017, 19(17), 4480-4483.
41. Oxidative Cleavage of Enamides with Hypervalent Iodine(III)/TMSN3 under an Air Atmosphere Ge Liu, Yan Li*, Jie Sheng, Xi-Sheng Wang* Synthesis 2017, 49(17), 3968-3974.
40. A Neutral Metal-Free System for Head-to-Tail Dimerization of Electron-Rich Alkenes A-Yun Luo, Yan Bao, Xiu-Fen Cheng, Xi-Sheng Wang* Synthesis 2017, 49(17), 3962-3967.
39. Copper-catalyzed oxidative C (sp 3)–H/C (sp 2)–H cross-coupling en route to carbocyclic rings Rui Wang, Yan Li, Ruo-Xing Jin, Xi-Sheng Wang* Chem. Sci. 2017, 8(5), 3838-3842.
2016
38. Nickel-Catalyzed C–H Trifluoromethylation of Electron-Rich Heteroarenes Yun Wu, Hao-Ran Zhang, Ruo-Xing Jin, Quan Lan, Xi-Sheng Wang* Adv. Synth. Catal. 2016, 358(22), 3528-3533. (Highlighted in Synfacts, 2017, 2, 138)
37. Nickel-Catalyzed Monofluoroalkylation of Arylsilanes via Hiyama Cross-Coupling Yun Wu, Hao-Ran Zhang, Yi-Xuan Cao, Quan Lan, Xi-Sheng Wang* Org. Lett. 2016, 18(21), 5564-5567. (Top 20 Most Downloaded Articles in October 2016)
36. Copper-Catalyzed Decarboxylative Atom Transfer Radical Addition of Iododifluoroacetate to Alkynyl Carboxylic Acids Gang Li#, Yi-Xuan Cao#, Chen-Guang Luo, Yi-Ming Su, Yan Li, Quan Lan, Xi-Sheng Wang* Org. Lett. 2016, 18(19), 4806-4809. (Top 20 Most Downloaded Articles in September 2016)
35. Direct electrophilic trifluoromethylthiolation of N-benzyl indoles using AgSCF3 Lan Ma, Xiu-Fen Cheng, Yan Li,* Xi-Sheng Wang* Tetrahedron Lett. 2016, 57(27-28), 2972-2975.
34. Palladium-Catalyzed C-7 Selective C-H Carbonylation of Indolines for Expedient Synthesis of Pyrroloquinazolinediones Pei-Long Wang, Yan Li*, Lan Ma, Chen-Guang Luo, Zhen-Yu Wang, Quan Lan, Xi-Sheng Wang* Adv. Synth. Catal. 2016, 358(7), 1048-1053.
33. Nickel-Catalyzed Decarboxylatvie Difluoroalkylation of α,β-Unsaturated Carboxylic Acids Gang Li, Tao Wang, Fan Fei, Yi-Ming Su, Yan Li, Quan Lan, Xi-Sheng Wang* Angew. Chem. Int. Ed. 2016, 55(10), 3491-3495.
2015
32. Pd-Catalyzed C(sp3)-H Carboxylation of Alkylamines: A Powerful Route to γ-Lactams and γ-Amino Acids Pei-Long Wang, Yan Li, Yun Wu, Chao Li, Quan Lan, Xi-Sheng Wang,* Org. Lett. 2015, 17(15), 3698-3701.
31. Nickel-Catalyzed Monofluoromethylation of Aryl Boronic Acids Yi-Ming Su, Guang-Shou Feng, Zhen-Yu Wang, Quan Lan, Xi-Sheng Wang,* Angew. Chem. Int. Ed. 2015, 54(20), 6003-6007.
30.Pd(II)-catalyzed, controllable C-H mono-/diarylation of aryl tetrazoles: concise synthesis of Losartan Yan-Jun Ding, Yan Li,* Sheng-Yu Dai, Quan Lan, Xi-Sheng Wang,* Org. Biomol. Chem. 2015, 13(11), 3198-3201.
29. Pd(II)-catalyzed C–H arylation of aryl and benzyl Weinreb amides Yan Wang, Kai Zhou, Quan Lan, Xi-Sheng Wang,* Org. Biomol. Chem. 2015, 13(2), 353-356.
Earlier
28. Palladium-Catalyzed C−F Bond Formation via Directed C-H Activation Yan Li, Yun Wu, Guang-Shui Li,* Xi-Sheng Wang,* Adv. Synth. Catal. 2014, 356(7), 1412-1418.
27. Visible Light-Mediated C−H Difluoromethylation of Electron-Rich Heteroarenes Yi-Ming Su, Yu Hou, Feng Yin, Yue-Ming Xu, Yan Li, Xiaoqi Zheng, Xi-Sheng Wang.* Org. Lett. 2014, 16(11), 2958-2961.
26. Iron-catalyzed radical aryldifluoromethylation of activated alkenes to difluoromethylated oxindoles Jian-Yong Wang, Xin Zhang, Yan Bao, Yue-Ming Xu, Xiu-Fen Cheng, Xi-Sheng Wang,* Org. Biomol. Chem. 2014, 12(30), 5582-5585. (Highlighted in Synfacts 2014, 10, 1136).
25. Pd(0)-Catalyzed radical aryldifluoromethylation of activated alkenes Jian-Yong Wang, Yi-Ming Su, Feng Yin, Yan Bao, Xin Zhang, Yue-Ming Xu, Xi-Sheng Wang,* Chem. Commun. 2014, 50(31), 4108-4111.
24. Silver-Mediated Radical Aryltrifluoromethylthiolaton of Activated Alkenes Feng Yin, Xi-Sheng Wang,* Org. Lett. 2014, 16(4), 1128-1131.
23. Rhodium-Catalyzed C–H Olefination of Aryl Weinreb Amides Yan Wang, Chao Li, Yan Li, Feng Yin,Xi-Sheng Wang* Adv. Synth. Catal. 2013, 355(9), 1724-1728.
22. Pd-Catalyzed C−H Lactonization for Expedient Synthesis of Biaryl Lactones and Total Synthesis of Cannabinol Yan Li, Yan-Jun Ding, Jian-Yong Wang, Yi-Ming Su, Xi-Sheng Wang,* Org. Lett. 2013, 15(11), 2574-2577. (Top 20 Read OL Articles in May 2013; Highlighted in Synfacts 2013, 9, 1057)
21. Pd(II)-Catalyzed Enantioselective C−H Activation/C−O Bond Formation: Synthesis of Chiral Benzofuranones Xiu-FenCheng†, Yan Li†, Yi-Ming Su, Feng Yin, Jian-Yong Wang, Jie Sheng, Harit U. Vora, Xi-Sheng Wang,* Jin-Quan Yu J. Am. Chem. Soc. 2013, 135(4), 1236-1239. (Top 20 Read JACS Articles in Jan. 2013; Highlight in Synfacts 2013, 9, 420; an Abstract in Organic Chemistry Portal)
Works Before Independence
20. Pd(II)-catalyzed para-selective C–H arylation of mono-substituted arenes Wang, X.; Leow, D.; Yu, J.-Q. J. Am. Chem. Soc. 2011, 133, 13864-13867. doi：10.1021/ja206572w
19. Palladium(II)-catalyzed selective monofluorination of benzoic zcids using a practical auxiliary: A weak-coordination approach Chan, K. S. L.; Wasa, M.; Wang, X.; Yu, J.-Q. Angew. Chem., Int. Ed. 2011, 50，9081-9084. DOI：10.1002/anie.201102985
18. Hydroxyl-directed C–H carbonylation enabled by mono-N-protected amino acid ligands: An expedient route to 1-isochromanones Lu, Y.; Leow, D.; Wang, X.; Yu, J.-Q. Chem. Sci. 2011, 2, 967-971. DOI:10.1039/C0SC00633E
17. Bystanding F+ Oxidants Enabled Selective Reductive Elimination from High-Valent Metal Centers in Catalysis Engle, K. E.; Mei, T.-S.; Wang, X.; Yu, J.-Q. Angew. Chem., Int. Ed. 2011, 51, 1478-1491.
16. Pd(II)-Catalyzed Hydroxyl-Directed C–H Activation/C–O Cyclization: Expedient Construction of Dihydrobenzofurans Wang, X.; Lu, Y.; Dai, H.-X.; Yu, J.-Q. J. Am. Chem. Soc. 2010, 132, 12203-12205.
15. Pd(II)-Catalyzed ortho-Trifluoromethylation of Arenes Using TFA as a Promoter Wang, X.; Truesdale, L.; Yu, J.-Q. J. Am. Chem. Soc. 2010, 132, 3648-3649.
14. Phase-Transfer Catalyzed Asymmetric Conjugate additions of b-Ketoesters to Acetylenic Ketones Lan, Q.; Wang, X.; Shirakawa, S.; Maruoka, K. Org. Process Res. Dev. 2010, 14, 684–686.
13. Chiral Bifunctional Phase Transfer Catalysts for Asymmetric Fluorination of b-Keto Esters Wang, X.; Lan, Q.; Shirakawa, S.; Maruoka, K. Chem. Commun. 2010, 46, 321-323.
12. Pd(II)-Catalyzed Amination of C–H Bonds Using Single-Electron or Two-Electron Oxidants Mei, T.-S.; Wang, X.; Yu, J.-Q. J. Am. Chem. Soc. 2009, 131, 10806-10807.
11. Versatile Pd(OTf)2·2H2O-Catalyzed ortho-Fluorination Using NMP as a Promoter Wang, X.; Mei, T.-S.; Yu, J.-Q. J. Am. Chem. Soc. 2009, 131, 7520-7521.
10. Highly Efficient Asymmetric Amination of b-Keto Esters Catalyzed by Chiral Quaternary Ammonium Bromides Lan, Q.; Wang, X.; He, R.; Ding, C.; Maruoka, K. Tetrahedron Lett. 2009, 50, 3280-3282.
9. Binaphthyl-Modified Quaternary Phosphonium Salts as Chiral Phase-Transfer Catalysts: Asymmetric Amination of b-Keto Esters He, R.; Wang, X.; Hashimoto, T.; Maruoka, K. Angew. Chem., Int. Ed. 2008, 47, 9466-9468.
8. Combinatorial Design of Simplified High-Performance Chiral Phase-Transfer Catalysts for Practical Asymmetric Synthesis of a-Alkyl- and a,a-Dialkyl-a-Amino Acids Kitamura, M.; Shirakawa, S.; Arimura, Y.; Wang, X.; Maruoka, K. Chem.–Asian J. 2008, 3, 1702-1714.
7. Convenient Preparation of Chiral Phase-Transfer Catalysts with Conformationally Fixed Biphenyl Core for Catalytic Asymmetric Synthesis of a-Alkyl- and a,a-Dialkyl-a-Amino Acids: Application to the Short Asymmetric Synthesis of BIRT-377 Wang, Y.-G.; Ueda, M.; Wang, X.; Han, Z.; Maruoka, K. Tetrahedron 2007, 63, 6042-6050.
6. Asymmetric Conjugate Additions of a-Substituted-a-Cyanoacetates to Acetylenic Ketones by Chiral Phase Transfer Catalysis Lan, Q.; Wang, X.; Maruoka, K. Tetrahedron Lett. 2007, 48, 4675-4678.
5. “Effects of Aromatic Substituents on Binaphthyl-Based Chiral Spiro-Type Ammonium Salts in Asymmetric Phase-Transfer Reactions” Kano, T.; Lan, Q.; Wang, X.; Maruoka, K. Adv. Synth. Catal. 2007, 349, 556-560.
4. New, Chiral Phase Transfer Catalysts for Effecting Asymmetric Conjugate Additions of a-Alkyl-a-Cyanoacetates to Acetylenic Esters Wang, X.; Kitamura, M.; Maruoka, K. J. Am. Chem. Soc. 2007, 129, 1038-1039.
2. One-Pot Enantioselective Aziridination of Olefins Catalyzed by a Copper(I) Complex of a Novel Diimine Ligand by Using PhI(OAc)2 and Sulfonamide as Nitrene Precursors Wang, X.; Ding, K. Chem.–Eur. J. 2006, 12, 4568-4575.
1. Self-Supported Heterogeneous Titanium Catalysts for Enantioselective Carbonyl-Ene and Sulfoxidation Reactions Wang, X.; Wang, X.; Guo, H.; Ding, K. Chem.–Eur. J. 2005, 11, 4078-4088.
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