80. Regio- and Atroposelective Ring-Opening of 1H-Benzo[4,5]oxazolopyridinones, Ruixian Deng*, Puyang Dong, Jimeng Ge, Wenjing Zhang, Xiaoping Xue, Longhui Duan, Linlin Shi*, Zhenhua Gu*, Angew. Chem. Int. Ed., 2024, 63, e202402231. DOI:10.1002/anie.202402231.
79. Rapid synthesis of benzofulvenes from α-bromodiarylethylenes based on a 1,4-palladium shift strategy, Abdur Rahim, Shuming Zhan, Biqiong Hong, Longhui Duan and Zhenhua Gu*, Org. Chem. Front., 2024. DOI:10.1039/d3qo01846f.
78. Conjugation-Induced Spin Delocalization in Helical Chiral Carbon Radicals via Through-Bond and Through-Space Effects, Longhui Duan, Xiaoping Xue,* Biqiong Hong, Zhenhua Gu*, Adv. Sci., 2023, 10, 202304563. DOI:10.1002/advs.202304563.
77. Aryl ortho methoxylation, Kun Zhao and Zhenhua Gu, Nature Chem., 2023, 15, 1334-1335 . DOI:10.1038/s41557-023-01323-w.
76. Preparation of Optically Active 2,2'-Dibromo-6,6'-diiodo -1,1'-biphenyl: A Powerful Precursor for Modular Synthesis of Functionalized Atropisomers, Yuanyuan Li, Longhui Duan, Biqiong Hong, and Zhenhua Gu*, Chin.J.Chem., 2023, 41, 3515-3520. DOI:10.1002/cjoc.202300438.
75. Expanding the Potential of 3-Hydroxyindolinones:Synthesis of Quinoxalin-2(1H)-ones through Acid-Promoted Azidation and Ring-Expansion, Shuming Zhan, Heng Xu, Lin Li, Wenjing Guo, Biqiong Hong, and Zhenhua Gu*, Adv.Synth.Catal., 2023, 365, 3450-3454. DOI:10.1002/adsc.202300685.
74. A Chiral Relay Race: Stereoselective Synthesis of Axially Chiral Biaryl Diketones through Ring-Opening of Optical Dihydrophenan-threne-9,10-diols, Lei Shi, Jiawei Zhu, Biqiong Hong, and Zhenhua Gu*, Molecules., 2023, 28, 5956. DOI:10.3390/molecules28165956.
73. Synthesis of atropisomers via transition-metal-catalyzed enantioselective carbene transformations, Chongqing Pan* and Zhenhua Gu*, Trends in Chem., 2023, 5, 684-696. DOI:10.1016/j.trechm.2023.05.005.
72. Stereoselective Synthesis Axially Chiral Arylnitriles through Base-Induced Chirality-Relay β-Carbon Elimination of α-Hydroxyl Ketoxime Esters, Xue Zhang, Xiaoping Xue, and Zhenhua Gu*, Org. Lett., 2023, 25, 3602-3606. DOI:10.1021/acs.orglett.3c00805.
71. Confronting the Challenge of Asymmetric Carbonyl Addition to Sterically Bulky Isatins: Upgrading Dirhodium(II)/Biphosphine Catalytic System, Wenjing Guo, Shuming Zhan, Han Yang, and Zhenhua Gu*, Org. Lett., 2023, 25, 3281-3286. DOI:10.1021/acs.orglett.3c01028.
70. Atroposelective Three-Component Coupling of Cyclic Diaryliodoniums and Sodium Cyanate Enabled by the Dual-Role of Phenol, Shan Yang, Tianze Zheng, Longhui Duan, Xiaoping Xue, and Zhenhua Gu*, Angew. Chem. Int. Ed., 2023, 62, e202302749. DOI:10.1002/anie.202302749.
69. Dirhodium(II)/Phosphine Catalyst with Chiral Environment at Bridging Site and Its Application in Enantioselective Atropisomer Synthesis, Lei Shi, Xiaoping Xue, Biqiong Hong, Qigang Li and Zhenhua Gu*, ACS Central Sci., 2023, 9, 748-755. DOI:10.1021/acscentsci.2c01207.
68. Divergent Synthesis of Helical Ketone Enabled by Rearrangement of Spiro Carbocation, Limin Wang, Longhui Duan, Biqiong Hong, and Zhenhua Gu*, Org. Lett., 2023, 25, 1912-1917. DOI:10.1021/acs.orglett.3c00424.
67. Recent Progress in Cyclic Aryliodonium Chemistry: Syntheses and Applications, Xiaopeng Peng, Abdur Rahim, Weijie Peng, Feng Jiang, Zhenhua Gu* and Shijun Wen* , Chem. Rev., 2023, 123, 1364-1416. DOI:10.1021/acs.chemrev.2c00591.
66. Two at the price of one: Kinetic resolution of multi-substituted metallocenes, Yuanyuan Li,Zhenhua Gu*, Sci. Bull., 2022, 67, 2502-2504 . DOI:10.1016/j.scib.2022.12.011.
65. Synthesis of Atropisomers with Biaryl and Vinylaryl Chirality via Pd-Catalyzed Point-to-Axial Chirality Transfer Ring-Opening Reaction, Jian Gu, Biqiong Hong, Xiaoping Xue, Junwei Xi, and Zhenhua Gu*, Org. Lett., 2022, 24, 9097-9101. DOI:10.1021/acs.orglett.2c03760.
64. Nitrenoid from Oxime: A Practical Synthesis of Planar Chiral Ferrocenyl Phenanthridines via Nitrene-Involved Ring-Expansion Reaction, Na Li,Biqiong Hong,Jinbo Zhao*,and Zhenhua Gu*, Angew. Chem.Int. Ed., 2023, 62, e202215530. DOI:10.1002/anie.202215530.
63. From Peripheral Stereogenic Center to Axial Chirality: Synthesis of 3-Arylthiophene Atropisomers, Lin Li,Junwei Xi,Biqiong Hong,Zhenhua Gu*, Adv. Synth.Catal., 2022, 364, 1-7. DOI:10.1002/adsc.202200957.
62. Synthesis of 2-Aryl Azetidines through Pd-Catalyzed Migration/Coupling of 3-Iodoazetidines and Aryl Boronic Acids, Han Yang, Zhen Chen, Wenjing Guo, and Zhenhua Gu*, Org. Lett., 2022, 24, 5731–5735. DOI:10.1021/acs.orglett.2c02152.
61. Transition Metal-Catalyzed Biaryl Atropisomer Synthesis via a Torsional Strain Promoted Ring-Opening Reaction, Xue Zhang, Kun Zhao, and Zhenhua Gu*, Acc. Chem. Res., 2022, 55, 1620-1633. DOI:10.1021/acs.accounts.2c00175.
60. Paddlewheel dirhodium(II) complexes with N-heterocyclic carbene or phosphine ligand: New reactivity and selectivity, Biqiong Hong, Lei Shi, Lin Li, Shuming Zhan, and Zhenhua Gu*, Green Synthesis and Catalysis., 2022, 3, 137-149. DOI:10.1016/j.gresc.2022.03.001.
59. Atroposelective Kinetic Resolution of 8H-Indeno[1,2-c]thiophen-8-ols via Pd-Catalyzed C–C Bond Cleavage Reaction, Junwei Xi, Han Yang, Lin Li, Xue Zhang, Chunyu Li, and Zhenhua Gu*, Org. Lett., 2022, 24, 2387–2392. DOI:10.1021/acs.orglett.2c00642.
58. Torsional strain inversed chemoselectivity in a Pd-catalyzed atroposelective carbonylation reaction of dibenzothiophenium, Qiuchi Zhang, Xiaoping Xue, Biqiong Hong, and Zhenhua Gu*, Chem. Sci. , 2022, 13, 3761-3765. DOI:10.1039/d2sc00341d.
57. Synthesis of 2-Hydroxy-2′-aroyl-1,1′-biaryls via Oxidative Ring-Opening of 9H-Fluoren-9-ols, Xiaoping Xue, Biqiong Hong, Jia Feng, and Zhenhua Gu*, Org. Lett., 2021, 24, 496-500. DOI:10.1021/acs.orglett.1c03849.
56. Construction of 2-Amino-2′-ketonyl Biaryls via Acid-Mediated Ring Opening of 9H-Fluoren-9-ols with Organic Azides, Shan Yang, Biqiong Hong, Jia Feng, and Zhenhua Gu*, Org. Lett., 2021, 23, 9179–9183. DOI:10.1021/acs.orglett.1c03484.
55. Ring-Expansion Strategy for α-Aryl Azahelicene Construction: Building Blocks for Optoelectronic Materials, Jia Feng, Limin Wang, Xiaoping Xue, Zengyin Chao, Biqiong Hong, and Zhenhua Gu*, Org. Lett., 2021, 23, 8056–8061. DOI:10.1021/acs.orglett.1c03070.
54. Synthesis of Planar Chiral 2-Aryl Aroylferrocenes via Palladium-Catalyzed C–C Bond-Cleavage/Ring-Opening Reaction, Zengyin Chao, Na Li, Biqiong Hong, Mingming Ma*, and Zhenhua Gu*, Org. Lett., 2021, 23, 7759−7764. DOI:10.1021/acs.orglett.1c02775.
53. Construction of Axial Chirality and Silicon-Stereogenic Center via Rh-Catalyzed Asymmetric Ring-Opening of Silafluorenes, Xiufen Bi, Jia Feng, Xiaoping Xue, and Zhenhua Gu*, Org. Lett., 2021, 23, 3201−3206. DOI:10.1021/acs.orglett.1c00935.
52. Enantioselective preparation of atropisomeric biaryl trifluoromethylsulfanes via ring-opening of cyclic diaryliodoniums, Longhui Duan, Zhonggui Wang, Kun Zhao and Zhenhua Gu*, Chem. Commun., 2021, 57, 3881–3884. DOI:10.1039/d1cc00171j.
51. Atropisomerism in Styrene: Synthesis, Stability, and Applications, Jia Feng and Zhenhua Gu*, SynOpen, 2021, 05, 68-85. DOI:10.1055/s-0040-1706028.
50. Transition‐Metal‐Catalyzed Carbon‐Carbon Bond Activation in Asymmetric Synthesis, Xiufen Bi, Qiuchi Zhang, and Zhenhua Gu*, Chin. J. Chem., 2021, ASAP. DOI:10.1002/cjoc.202000591.
49. Diols Activation via Cu/Borinic Acids Synergistic Catalysis in Atroposelective Ring‐Opening of Cyclic Diaryliodoniums, Kun Zhao†, Shan Yang†, Qi Gong, Longhui Duan, and Zhenhua Gu*, Angew. Chem. Int. Ed., 2021, 60, 5788–5793. DOI:10.1002/anie.202014127 († K.Z. and S.Y. contributed equally to this work).
48. Catalytic Asymmetric Synthesis of Atropisomeric Nitrones: Versatile Intermediate for Axially Chiral Biaryls, Wenjing Guo, Jian Gu, and Zhenhua Gu*, Org. Lett., 2020, 22, 7622–7628. DOI:10.1021/acs.orglett.0c02830
47. Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl Narasaka acylation, Jia Feng†, Xiufen Bi†, Xiaoping Xue, Na Li, Lei Shi and Zhenhua Gu*, Nat. Commun., 2020, 11, 4449. DOI:10.1038/s41467-020-18273-3 († J. F. and X. B. contributed equally to this work).
46. Cu-Catalyzed Site- and Enantioselective Ring-Opening of Cyclic Diaryliodoniums with 1,2,3-Triazoles, Zengyin Chao, Mingming Ma*, and Zhenhua Gu*, Org. Lett., 2020, 22, 6441–6446. DOI:10.1021/acs.orglett.0c02256
45. Atroposelective Ring Opening of Cyclic Diaryliodonium Salts with Bulky Anilines Controlled by a Chiral Cobalt(III) Anion, Xue Zhang, Kun Zhao, Na Li, Jie Yu*, Liu-Zhu Gong and Zhenhua Gu*, Angew. Chem. Int. Ed. , 2020, 59, 19899–19904. DOI:10.1002/anie.202008431
44. Palladium‐Catalyzed Atroposelective 16‐Membered Macrocyclization: Total Synthesis of Isoplagiochin D, Junwei Xi Zhenhua Gu*, Chin. J. Chem. , 2020, 38, 1081-1085. DOI:10.1002/cjoc.202000051
43. Hypervalent Iodine‐Mediated Carbon‐Carbon Bond Cleavage and Dearomatization of 9H-Fluoren-9-ols, Ruixian Deng, Shuming Zhan, Chunyu Li and Zhenhua Gu*, Angew. Chem. Int. Ed. , 2020, 59, 3093–3098. DOI:10.1002/anie.201913373
42. Enantioselective Ring-Opening/Oxidative Phosphorylation and P-Transfer Reaction of Cyclic Diaryliodoniums, Longhui Duan, Kun Zhao, Zhonggui Wang, Feng-Lian Zhang* and Zhenhua Gu*, ACS Catal., 2019, 9, 9852-9858. DOI:10.1021/acscatal.9b03454
41. Copper-Catalyzed Enantioselective Ring-Opening of Cyclic Diaryliodoniums and O-Alkylhydroxylamines, Qigang Li, Mingkai Zhang, Shuming Zhan, Zhenhua Gu*, Org. Lett., 2019, 21, 6374-6377. DOI:10.1021/acs.orglett.9b02267
40. 1,4‐Migration of Transition Metals in Organic Synthesis, Abdur Rahim, Jia Feng, Zhenhua Gu*, Chin. J. Chem. , 2019, 37, 929–945. DOI:10.1002/cjoc.201900180
39. Synthesis of Bridged Biaryl Atropisomers via Sequential Cu- and Pd-Catalyzed Asymmetric Ring Opening and Cyclization, Xiaoping Xue, Zhenhua Gu*, Org. Lett., 2019, 21, 3942–3945. DOI:10.1021/acs.orglett.9b01062
38. Enantioselective Carbon-Carbon
Bond Cleavage for Biaryl Atropisomers Synthesis, Ruixian Deng†, Junwei Xi†, Qigang Li, Zhenhua
Gu*, Chem, 2019, 5, 1834-1846. DOI:10.1016/j.chempr.2019.04.008 († R.
D. and J. X. contributed equally.)
37. Selective Ortho Thiolation Enabled by Tuning the Ancillary Ligand in Palladium/Norbornene Catalysis, Wenqiang Cai, Zhenhua Gu*, Org. Lett., 2019, 21 (9), 3204–3209. DOI:10.1021/acs.orglett.9b00923
36. Enantioselective Atropisomeric Anilides Synthesis via Cu-Catalyzed Intramolecular Adjacent C–N Coupling, Xiaozhong Fan, Xue Zhang, Chunyu Li, Zhenhua Gu*, ACS Catal., 2019, 9, 2286–2291. DOI:10.1021/acscatal.8b04789
35. Development of New Electrophiles in Palladium/Norbornene-Catalyzed ortho-Functionalization of Aryl Halides, Kun Zhao, Linlin Ding, Zhenhua Gu*, Synlett 2018, 29, 129–140. DOI:10.1055/s-0037-1611057
34. Cu-Catalyzed Enantioselective Atropisomer Synthesis via Thiolative Ring Opening of Five-Membered Cyclic Diaryliodoniums, Mengqing Hou, Ruixian Deng, Zhenhua Gu*, Org. Lett., 2018, 20 (18), 5779–5783. DOI:10.1021/acs.orglett.8b02477
33. Cu-Catalyzed Enantioselective Ring Opening of Cyclic Diaryliodoniums toward the Synthesis of Chiral Diarylmethanes, Bin Li, Zengyin Chao, Chunyu Li, Zhenhua Gu*, J. Am. Chem. Soc., 2018, 140 (30), 9400–9403. DOI:10.1021/jacs.8b05743.
32. VIP: Copper‐catalyzed Asymmetric Ring‐opening of Cyclic Diaryliodonium with Benzyl and Aliphatic Amines, Shibo Xu†, Kun Zhao†, Zhenhua Gu*, Adv. Synth. Catal., 2018, 360, 3877-3883. DOI:10.1002/adsc.201800637 († S. X. and K. Z. contributed equally to this work).
31. Unusual Biaryl Torsional Strain Promoted Reactivity in Cu-Catalyzed Sommelet-Hauser Rearrangement, Chongqing Pan, Wenjing Guo, Zhenhua Gu*, Chem. Sci., 2018, 9, 5850-5854. DOI:10.1039/C8SC01657G
30. Enantioselective Synthesis of Biaryl Atropisomers via Pd/Norbornene-Catalyzed Three-Component Cross-Couplings, Linlin Ding, Xianwei Sui, Zhenhua Gu*, ACS Catal., 2018, 8, 5630–5635, DOI:10.1021/acscatal.8b01037
29. Enhanced Reactivity by Torsional Strain of Cyclic Diaryliodonium in Cu-Catalyzed Enantioselective Ring-Opening Reaction, Kun Zhao†, Longhui Duan†, Shibo Xu, Julong Jiang, Yao Fu*, and Zhenhua Gu*(Lead Contact), Chem, 2018, 4, p599–612, This work was highlighted by X-Mol, DOI:10.1016/j.chempr.2018.01.017 († K. Z. and L. D. contributed equally).
28. Palladium/Norbornene-Catalyzed Ortho-Acylation and Ipso-Selenation via C(O)–Se Bond Cleavage: Synthesis of α-Carbonyl Selane, Xiaozhong Fan, Zhenhua Gu*, Org. Lett., 2018, 20 (4), 1187–1190, DOI:10.1021/acs.orglett.8b00112.
27. Palladium/Norbornene-Catalyzed ortho Aliphatic Acylation with Mixed Anhydride: Selectivity and Reactivity, Shibo Xu†, Julong Jiang† , Linlin Ding, Yao Fu*, and Zhenhua Gu*, Org. Lett., 2018, 20 (2), 325–328, DOI:10.1021/acs.orglett.7b03514.
26. Visible Light Accelerated Vinyl C-H Arylation in Pd-Catalysis: Application in the Synthesis of ortho Tetra-substituted Vinylarene Atropisomers , Jia Feng† , Bin Li† , Julong Jiang, Mingkai Zhang, Wenbai Ouyang, Chunyu Li, Yao Fu*, Zhenhua Gu*, Chin. J. Chem. 2018, 36, 11-14. ,DOI:10.1002/cjoc.201700618.
25. Enantioselective Synthesis of Indole-Based Biaryl Atropisomers via Palladium-Catalyzed Dynamic Kinetic Intramolecular C-H Cyclization , Congfa He, Mengqing Hou, Zixi Zhu, Zhenhua Gu*, ACS Catal., 2017, 7 (8), 5316–5320 ,DOI:10.1021/acscatal.7b01855.
24. Synthesis of 2,3-dihydro-1H-phosphindole-1-oxides via the t-BuLi-mediated rearrangement of vinyl bromides and phosphine oxides, Bin Li, Mingkai Zhang, Xulun Huang, Zhenhua Gu**, Org. Chem. Front., 2017, 4, 1854–1857, DOI:10.1039/c7qo00310b
23. Palladium-Catalyzed Enantioselective Synthesis of 2-Aryl Cyclohex-2-enone Atropisomers: Platform Molecules for the Divergent Synthesis of Axially Chiral Biaryl Compounds, Chongqing Pan, Zixi Zhu, Mingkai Zhang, Zhenhua Gu*, Angew. Chem. Int. Ed. 2017, 56, 4777 –4781,DOI:10.1002/anie.201701467.
22. Synthesis of Chiral Cleft C,N-Palladium and Iridium Complexes from 2,3:6,7-Dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-dione and Their Synthetic Applications, Congfa He, Bin Wang, Mingli Gao*, Zhenhua Gu* , Organometallics, 2017, 36 (5), 1073–1078, DOI:10.1021/acs.organomet.7b00024.
21. Total Synthesis of Aquatolide: Wolff Ring Contraction and Late-Stage Nozaki–Hiyama–Kishi Medium-Ring Formation, Bin Wang†, Yuanzhen Xie†, Qin Yang‡, Guozhu Zhang*‡, Zhenhua Gu*†, Org. Lett., 2016, 18 (20), 5388–5391, DOI:10.1021/acs.orglett.6b02767.
20. Catalytically Asymmetric Pd/Norbornene Catalysis: Enantioselective Synthesis of (+)-Rhazinal, (+)-Rhazinilam, and (+)-Kopsiyunnanine C1–3, Kun Zhao, Shibo Xu, Chongqing Pan, Xianwei Sui, Zhenhua Gu*, Org. Lett., 2016, 18 (15), 3782–3785, DOI:10.1021/acs.orglett.6b01790.
19. Cleavage of the C(O)–S Bond of Thioesters by Palladium/Norbornene/Copper Cooperative Catalysis: An Efficient Synthesis of 2-(Arylthio)aryl Ketones, Fenggang Sun, Miao Li, Congfa He, Bin Wang, Bin Li, Xianwei Sui, Zhenhua Gu*, J. Am. Chem. Soc., 2016, 138 (24), 7456–7459, DOI:10.1021/jacs.6b02495.
18. Enantioselective Synthesis of Atropisomeric Vinyl Arene Compounds by Palladium Catalysis: A Carbene Strategy, Jia Feng† , Bin Li† , Yun He, Zhenhua Gu*, Angew. Chem. Int. Ed. 2016, 55, 2186 –2190, DOI:10.1002/anie.201509571(J. F. and B. L. contributed equally).
17. Synthesis of 2-(1-Alkoxyvinyl)anilines by Palladium/Norbornene-Catalyzed Amination Followed by Termination with Vinyl Ethers, Jie Wang, Zhenhua Gu*, Adv. Synth. Catal. , 2016, 358, 2990–2995, DOI:10.1002/adsc.201600339.
16. The palladium/norbornene-catalyzed ortho-silylmethylation reaction: a practical protocol for ortho-functionalized one-carbon homologation of aryl iodides, Xianwei Sui, Linlin Ding, Zhenhua Gu*, Chem. Commun., 2016, 52, 13999-14002, DOI:10.1039/C6CC08227K.
15. Pd/norbornene-catalyzed sequential ortho-C–H alkylation and ipso-alkynylation: a 1,1-dimethyl-2-alkynol strategy, Fenggang Sun, Miao Li, Zhenhua Gu *, Org. Chem. Front., 2016, 3, 309-313 , DOI: 10.1039/C5QO00391A.
14. A Catalyst-Free Synthesis of Phosphinic Amides Using O-Benzoylhydroxylamines, Rui Zhu, Chongqing Pan, Zhenhua Gu*, Org. Lett., 2015, 17 (23), pp 5862–5865 , DOI:10.1021/acs.orglett.5b03056.
13. Palladium-Catalyzed Catellani ortho-Acylation Reaction: An Efficient and Regiospecific Synthesis of Diaryl Ketones, Yunze Huang, Rui Zhu, Kun Zhao, Zhenhua Gu*, Angew. Chem., Int. Ed. 2015, 54, 12669–12672. DOI:10.1002/anie.201506446.
12. BF3. OEt2-Promoted Synthesis of 2, 3-Metallocenocyclohexanones: A 1, 2-Hydride Shift and Cationic Cyclization Strategy. Congfa He, Wang Jie; Zhenhua Gu*, J. Org. Chem. 2015, 80, 7865-7875, DOI: 10.1021/acs.joc.5b01511
11. Decarboxylative Alkynyl Termination of Palladium-Catalyzed Catellani Reaction: A Facile Synthesis of alpha-Alkynyl Anilines via Ortho C-H Amination and Alkynylation, Fenggang Sun, Zhenhua Gu*, Org. Lett. 2015, 17,2222-2225, DOI: 10.1021/acs.orglett.5b00830.
10. Palladium-Catalyzed Heck-type Domino Cyclization and Carboxylation to Synthesize Carboxylic Acids by Utilizing Chloroform as the Carbon Monoxide Source, Xianglei Liu, Bin Li, and Zhenhua Gu, J. Org. Chem. 2015, 80 (15), 7547–7554. DOI: 10.1021/acs.joc.5b01126.
9. Pd-catalyzed Heck cyclization and in situ hydrocarboxylation or hydromethenylation via a hydrogen borrowing strategy, Xianglei Liu and Zhenhua Gu*, Org. Chem. Front. 2015, 2, 778-782, DOI: 10.1039/c5qo00091b.
8. Stereoselective Synthesis of 1,3-Amino Alcohols by the Pd-CatalyzedCyclization of Trichloroacetimidates, Yuanzhen Xie, Kai Yu, and Zhenhua Gu*, J. Org. Chem. 2014, 79, 1289-1302, DOI: 10.1021/jo402681z.
7. Palladium-Catalyzed Intramolecular Asymmetric C-H Functionalization/Cyclization Reaction of Metallocenes: An Efficient Approach toward the Synthesis of Planar Chiral Metallocene Compounds, Ruixian Deng,† Yunze Huang,† Xinna Ma, Gencheng Li, Rui Zhu, Bin Wang, Yan-Biao Kang,* and Zhenhua Gu*, J. Am. Chem. Soc. 2014, 136, 4472-4475, DOI: 10.1021/ja500699x.(R. D. and Y. H. contributed equally)
6. N-Bromoacetamide-mediated domino cyclization and elimination of homoallylic trichloroacetimidates: a novel approach toward the synthesis of 1-bromo-2-amino-3-butene derivatives, Rui Zhu, Kai Yu and Zhenhua Gu*, Org. Biomol. Chem. 2014, 12, 6653-6660, DOI: 10.1039/c4ob01126k.(R. Z. and K. Y. contributed equally)
5. Highly efficient and practical resolution of 2,3:6,7- dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-dione and stereoselective synthesis of its chiral diamine derivatives, Bin Wang and Zhenhua Gu*, Org. Chem. Front. 2014, 1, 271-274, DOI: 10.1039/c4qo00011k.
4. Palladium-catalyzed intramolecular Cp–H bond functionalization/arylation: an enantioselective approach to planar chiral quinilinoferrocenes, Xinna Ma, and Zhenhua Gu*，RSC Adv., 2014, 4, 36241–36244，DOI: 10.1039/c4ra07832b.
3. 一种拆分手性二酮化合物的方法，发明人：顾振华；王斌等，专利号：ZL 2013 1 0438421.8。
2. Pd-Catalyzed Heck-Type Cascade Reactions with N-Tosyl Hydrazones: An Efficient Way to Alkenes via in Situ Generated Alkylpalladium, Xianglei Liu, Xinna Ma, Yunze Huang, and Zhenhua Gu*, Org. Lett. 2013, 15 (18), 4814-4817, DOI: 10.1021/ol402210a.
1. Pd-Catalyzed Chemoselective Catellani Ortho-Arylation of Iodopyrroles: Rapid Total Synthesis of Rhazinal，Xianwei Sui, Rui Zhu, Gencheng Li, Xinna Ma, and Zhenhua Gu*，J. Am. Chem. Soc. 2013, 135, 9318-9321，DOI: 10.1021/ja404494u. This work was highlighted by Synlett 2013, 24, 2023-2031, DOI: 10.1055/s-0033-1339756.(X. S. and R. Z. contributed equally)
