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85. Coplanar Atropochiral 5H-Cyclopenta[2,1-b:3,4-b']dipyridine Ligands: Synthesis and Applications in Asymmetric Ring-Opening Reaction, Han Yang, Xiaojie Sun, Zhen Chen, Chenming Jiang, Longhui Duan, Jinbo Zhao, Zhenhua Gu*, Angew. Chem. Int. Ed., 2024,e202416839. DOI:10.1002/anie.202416839.
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83. Spatial decoupling of bromide-mediated process boosts propylene oxide electrosynthesis, Mingfang Chi, Jingwen Ke, Yan Liu, Miaojin Wei, Hongliang Li, Jiankang Zhao, Yuxuan Zhou, Zhenhua Gu, Zhigang Geng* and Jie Zeng*, Nat. Commun., 2024, 15, 3646. DOI:10.1038/s41467-024-48070-1.
82. Symmetric Anion Mediated Dynamic Kinetic Asymmetric Knoevenagel Reaction for N−C and N−N Atropisomers Synthesis, Hongyu Qu, Chenyang Huo, Jimeng Ge, Xiaoping Xue*, Zhenhua Gu and Ruixian Deng*, Angew. Chem. Int. Ed., 2024, 63, e202410012. DOI:10.1002/anie.202410012.
81. Kinetic Resolution of Helicenols via Palladium-Catalyzed Atroposelective C–C Bond Cleavage/Ring-Opening Reaction, Zhen Chen, Han Yang, Lin Li, Longhui Duan*, Junwei Xi, and Zhenhua Gu*, Org. Lett., 2024, 26,3429–3434 DOI:10.1021/acs.orglett.4c00962.
80. Regio- and Atroposelective Ring-Opening of 1H-Benzo[4,5]oxazolopyridinones, Ruixian Deng*, Puyang Dong, Jimeng Ge, Wenjing Zhang, Xiaoping Xue, Longhui Duan, Linlin Shi*, Zhenhua Gu*, Angew. Chem. Int. Ed., 2024, 63, e202402231. DOI:10.1002/anie.202402231.
79. Rapid synthesis of benzofulvenes from α-bromodiarylethylenes based on a 1,4-palladium shift strategy, Abdur Rahim, Shuming Zhan, Biqiong Hong, Longhui Duan and Zhenhua Gu*, Org. Chem. Front., 2024. DOI:10.1039/d3qo01846f.
78. Conjugation-Induced Spin Delocalization in Helical Chiral Carbon Radicals via Through-Bond and Through-Space Effects, Longhui Duan, Xiaoping Xue,* Biqiong Hong, Zhenhua Gu*, Adv. Sci., 2023, 10, 202304563. DOI:10.1002/advs.202304563.
77. Aryl ortho methoxylation, Kun Zhao and Zhenhua Gu, Nature Chem., 2023, 15, 1334-1335 . DOI:10.1038/s41557-023-01323-w.
76. Preparation of Optically Active 2,2'-Dibromo-6,6'-diiodo -1,1'-biphenyl: A Powerful Precursor for Modular Synthesis of Functionalized Atropisomers, Yuanyuan Li, Longhui Duan, Biqiong Hong, and Zhenhua Gu*, Chin.J.Chem., 2023, 41, 3515-3520. DOI:10.1002/cjoc.202300438.
75. Expanding the Potential of 3-Hydroxyindolinones:Synthesis of Quinoxalin-2(1H)-ones through Acid-Promoted Azidation and Ring-Expansion, Shuming Zhan, Heng Xu, Wenjing Guo, Lin Li, Biqiong Hong, and Zhenhua Gu*, Adv.Synth.Catal., 2023, 365, 3450-3454. DOI:10.1002/adsc.202300685.
74. A Chiral Relay Race: Stereoselective Synthesis of Axially Chiral Biaryl Diketones through Ring-Opening of Optical Dihydrophenan-threne-9,10-diols, Lei Shi, Jiawei Zhu, Biqiong Hong, and Zhenhua Gu*, Molecules., 2023, 28, 5956. DOI:10.3390/molecules28165956.
73. Synthesis of atropisomers via transition-metal-catalyzed enantioselective carbene transformations, Chongqing Pan* and Zhenhua Gu*, Trends in Chem., 2023, 5, 684-696. DOI:10.1016/j.trechm.2023.05.005.
72. Stereoselective Synthesis Axially Chiral Arylnitriles through Base-Induced Chirality-Relay β-Carbon Elimination of α-Hydroxyl Ketoxime Esters, Xue Zhang, Xiaoping Xue, and Zhenhua Gu*, Org. Lett., 2023, 25, 3602-3606. DOI:10.1021/acs.orglett.3c00805.
71. Confronting the Challenge of Asymmetric Carbonyl Addition to Sterically Bulky Isatins: Upgrading Dirhodium(II)/Biphosphine Catalytic System, Wenjing Guo, Shuming Zhan, Han Yang, and Zhenhua Gu*, Org. Lett., 2023, 25, 3281-3286. DOI:10.1021/acs.orglett.3c01028.
70. Atroposelective Three-Component Coupling of Cyclic Diaryliodoniums and Sodium Cyanate Enabled by the Dual-Role of Phenol, Shan Yang, Tianze Zheng, Longhui Duan, Xiaoping Xue, and Zhenhua Gu*, Angew. Chem. Int. Ed., 2023, 62, e202302749. DOI:10.1002/anie.202302749.
69. Dirhodium(II)/Phosphine Catalyst with Chiral Environment at Bridging Site and Its Application in Enantioselective Atropisomer Synthesis, Lei Shi, Xiaoping Xue, Biqiong Hong, Qigang Li and Zhenhua Gu*, ACS Central Sci., 2023, 9, 748-755. DOI:10.1021/acscentsci.2c01207.
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67. Recent Progress in Cyclic Aryliodonium Chemistry: Syntheses and Applications, Xiaopeng Peng, Abdur Rahim, Weijie Peng, Feng Jiang, Zhenhua Gu* and Shijun Wen* , Chem. Rev., 2023, 123, 1364-1416. DOI:10.1021/acs.chemrev.2c00591.
66. Two at the price of one: Kinetic resolution of multi-substituted metallocenes, Yuanyuan Li,Zhenhua Gu*, Sci. Bull., 2022, 67, 2502-2504 . DOI:10.1016/j.scib.2022.12.011.
65. Synthesis of Atropisomers with Biaryl and Vinylaryl Chirality via Pd-Catalyzed Point-to-Axial Chirality Transfer Ring-Opening Reaction, Jian Gu, Biqiong Hong, Xiaoping Xue, Junwei Xi, and Zhenhua Gu*, Org. Lett., 2022, 24, 9097-9101. DOI:10.1021/acs.orglett.2c03760.
64. Nitrenoid from Oxime: A Practical Synthesis of Planar Chiral Ferrocenyl Phenanthridines via Nitrene-Involved Ring-Expansion Reaction, Na Li,Biqiong Hong,Jinbo Zhao*,and Zhenhua Gu*, Angew. Chem.Int. Ed., 2023, 62, e202215530. DOI:10.1002/anie.202215530.
63. From Peripheral Stereogenic Center to Axial Chirality: Synthesis of 3-Arylthiophene Atropisomers, Lin Li,Junwei Xi,Biqiong Hong,Zhenhua Gu*, Adv. Synth.Catal., 2022, 364, 1-7. DOI:10.1002/adsc.202200957.
62. Synthesis of 2-Aryl Azetidines through Pd-Catalyzed Migration/Coupling of 3-Iodoazetidines and Aryl Boronic Acids, Han Yang, Zhen Chen, Wenjing Guo, and Zhenhua Gu*, Org. Lett., 2022, 24, 5731–5735. DOI:10.1021/acs.orglett.2c02152.
61. Transition Metal-Catalyzed Biaryl Atropisomer Synthesis via a Torsional Strain Promoted Ring-Opening Reaction, Xue Zhang, Kun Zhao, and Zhenhua Gu*, Acc. Chem. Res., 2022, 55, 1620-1633. DOI:10.1021/acs.accounts.2c00175.
60. Paddlewheel dirhodium(II) complexes with N-heterocyclic carbene or phosphine ligand: New reactivity and selectivity, Biqiong Hong, Lei Shi, Lin Li, Shuming Zhan, and Zhenhua Gu*, Green Synthesis and Catalysis., 2022, 3, 137-149. DOI:10.1016/j.gresc.2022.03.001.
59. Atroposelective Kinetic Resolution of 8H-Indeno[1,2-c]thiophen-8-ols via Pd-Catalyzed C–C Bond Cleavage Reaction, Junwei Xi, Han Yang, Lin Li, Xue Zhang, Chunyu Li, and Zhenhua Gu*, Org. Lett., 2022, 24, 2387–2392. DOI:10.1021/acs.orglett.2c00642.
58. Torsional strain inversed chemoselectivity in a Pd-catalyzed atroposelective carbonylation reaction of dibenzothiophenium, Qiuchi Zhang, Xiaoping Xue, Biqiong Hong, and Zhenhua Gu*, Chem. Sci. , 2022, 13, 3761-3765. DOI:10.1039/d2sc00341d.
57. Synthesis of 2-Hydroxy-2′-aroyl-1,1′-biaryls via Oxidative Ring-Opening of 9H-Fluoren-9-ols, Xiaoping Xue, Biqiong Hong, Jia Feng, and Zhenhua Gu*, Org. Lett., 2021, 24, 496-500. DOI:10.1021/acs.orglett.1c03849.
56. Construction of 2-Amino-2′-ketonyl Biaryls via Acid-Mediated Ring Opening of 9H-Fluoren-9-ols with Organic Azides, Shan Yang, Biqiong Hong, Jia Feng, and Zhenhua Gu*, Org. Lett., 2021, 23, 9179–9183. DOI:10.1021/acs.orglett.1c03484.
55. Ring-Expansion Strategy for α-Aryl Azahelicene Construction: Building Blocks for Optoelectronic Materials, Jia Feng, Limin Wang, Xiaoping Xue, Zengyin Chao, Biqiong Hong, and Zhenhua Gu*, Org. Lett., 2021, 23, 8056–8061. DOI:10.1021/acs.orglett.1c03070.
54. Synthesis of Planar Chiral 2-Aryl Aroylferrocenes via Palladium-Catalyzed C–C Bond-Cleavage/Ring-Opening Reaction, Zengyin Chao, Na Li, Biqiong Hong, Mingming Ma*, and Zhenhua Gu*, Org. Lett., 2021, 23, 7759−7764. DOI:10.1021/acs.orglett.1c02775.
53. Construction of Axial Chirality and Silicon-Stereogenic Center via Rh-Catalyzed Asymmetric Ring-Opening of Silafluorenes, Xiufen Bi, Jia Feng, Xiaoping Xue, and Zhenhua Gu*, Org. Lett., 2021, 23, 3201−3206. DOI:10.1021/acs.orglett.1c00935.
52. Enantioselective preparation of atropisomeric biaryl trifluoromethylsulfanes via ring-opening of cyclic diaryliodoniums, Longhui Duan, Zhonggui Wang, Kun Zhao and Zhenhua Gu*, Chem. Commun., 2021, 57, 3881–3884. DOI:10.1039/d1cc00171j.
51. Atropisomerism in Styrene: Synthesis, Stability, and Applications, Jia Feng and Zhenhua Gu*, SynOpen, 2021, 05, 68-85. DOI:10.1055/s-0040-1706028.
50. Transition‐Metal‐Catalyzed Carbon‐Carbon Bond Activation in Asymmetric Synthesis, Xiufen Bi, Qiuchi Zhang, and Zhenhua Gu*, Chin. J. Chem., 2021, ASAP. DOI:10.1002/cjoc.202000591.
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48. Catalytic Asymmetric Synthesis of Atropisomeric Nitrones: Versatile Intermediate for Axially Chiral Biaryls, Wenjing Guo, Jian Gu, and Zhenhua Gu*, Org. Lett., 2020, 22, 7622–7628. DOI:10.1021/acs.orglett.0c02830
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46. Cu-Catalyzed Site- and Enantioselective Ring-Opening of Cyclic Diaryliodoniums with 1,2,3-Triazoles, Zengyin Chao, Mingming Ma*, and Zhenhua Gu*, Org. Lett., 2020, 22, 6441–6446. DOI:10.1021/acs.orglett.0c02256
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35. Development of New Electrophiles in Palladium/Norbornene-Catalyzed ortho-Functionalization of Aryl Halides, Kun Zhao, Linlin Ding, Zhenhua Gu*, Synlett 2018, 29, 129–140. DOI:10.1055/s-0037-1611057
34. Cu-Catalyzed Enantioselective Atropisomer Synthesis via Thiolative Ring Opening of Five-Membered Cyclic Diaryliodoniums, Mengqing Hou, Ruixian Deng, Zhenhua Gu*, Org. Lett., 2018, 20 (18), 5779–5783. DOI:10.1021/acs.orglett.8b02477
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28. Palladium/Norbornene-Catalyzed Ortho-Acylation and Ipso-Selenation via C(O)–Se Bond Cleavage: Synthesis of α-Carbonyl Selane, Xiaozhong Fan, Zhenhua Gu*, Org. Lett., 2018, 20 (4), 1187–1190, DOI:10.1021/acs.orglett.8b00112.
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21. Total Synthesis of Aquatolide: Wolff Ring Contraction and Late-Stage Nozaki–Hiyama–Kishi Medium-Ring Formation, Bin Wang†, Yuanzhen Xie†, Qin Yang‡, Guozhu Zhang*‡, Zhenhua Gu*†, Org. Lett., 2016, 18 (20), 5388–5391, DOI:10.1021/acs.orglett.6b02767.
20. Catalytically Asymmetric Pd/Norbornene Catalysis: Enantioselective Synthesis of (+)-Rhazinal, (+)-Rhazinilam, and (+)-Kopsiyunnanine C1–3, Kun Zhao, Shibo Xu, Chongqing Pan, Xianwei Sui, Zhenhua Gu*, Org. Lett., 2016, 18 (15), 3782–3785, DOI:10.1021/acs.orglett.6b01790.
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1. Pd-Catalyzed Chemoselective Catellani Ortho-Arylation of Iodopyrroles: Rapid Total Synthesis of Rhazinal，Xianwei Sui, Rui Zhu, Gencheng Li, Xinna Ma, and Zhenhua Gu*，J. Am. Chem. Soc. 2013, 135, 9318-9321，DOI: 10.1021/ja404494u. This work was highlighted by Synlett 2013, 24, 2023-2031, DOI: 10.1055/s-0033-1339756.(X. S. and R. Z. contributed equally)
